467448
Triethylsilane
97%
Synonym(s):
NSC 93579, Triethylhydrosilane, Triethylsilicon hydride
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About This Item
Linear Formula:
(C2H5)3SiH
CAS Number:
Molecular Weight:
116.28
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-535-3
Beilstein/REAXYS Number:
1098278
MDL number:
Assay:
97%
Quality Level
assay
97%
reaction suitability
reagent type: reductant
refractive index
n20/D 1.412 (lit.)
bp
107-108 °C (lit.)
density
0.728 g/mL at 25 °C (lit.)
SMILES string
CC[SiH](CC)CC
InChI
1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
InChI key
AQRLNPVMDITEJU-UHFFFAOYSA-N
Application
Triethylsilane can be used as:
- A reducing agent in the regioselective reductive coupling of enones and allenes.
- A reagent in the redox initiated cationic polymerization.
- A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
- As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.
Catalyst for:
Catalyst reactivation after catalyst polymerization of styrene
Studies involving the prediction of organosilicon flash points
- Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
- Redox initiated cationic polymerization
- Beckmann rearrangement of cyclododecanone oxime
- Regioselective reductive coupling of enones and allenes
Catalyst reactivation after catalyst polymerization of styrene
Studies involving the prediction of organosilicon flash points
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signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
21.2 °F
flash_point_c
-6 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Iridium-catalyzed reduction of alkyl halides by triethylsilane.
Yang J and Brookhart M
Journal of the American Chemical Society, 129(42), 12656-12657 (2007)
Triethylsilane- Indium (III) Chloride System as a Radical Reagent.
Hayashi N, et al.
Organic Letters, 6(26), 4981-4983 (2004)
Pd- C-induced catalytic transfer hydrogenation with triethylsilane.
Mandal PK and McMurray JS
The Journal of Organic Chemistry, 72(17), 6599-6601 (2007)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 467448-100ML | 04061838119902 |
| 467448-25ML | 04061832358130 |
| 467448-PZ | 04061824742008 |