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Merck
CN

481521

Hexaamminecobalt(III) chloride

99%

Synonym(s):

Cobalt hexammine trichloride, Hexaamminecobalt trichloride

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About This Item

Linear Formula:
[Co(NH3)6]Cl3
CAS Number:
Molecular Weight:
267.48
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
234-103-9
MDL number:
Assay:
99%
Form:
powder
Solubility:
H2O: slightly soluble(lit.), ethanol: insoluble(lit.)
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Quality Level

assay

99%

form

powder

mp

217 °C (lit.)

solubility

H2O: slightly soluble(lit.), ethanol: insoluble(lit.)

density

1.71 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Co+3]

InChI

1S/3ClH.Co.6H3N/h3*1H;;6*1H3/q;;;+3;;;;;;/p-3

InChI key

JXBGZYGSWFSYFI-UHFFFAOYSA-K

General description

Hexaamminecobalt(III) chloride can be used as a starting material to prepare various Co-based nanomaterials such as Co-Sb nanoalloys, Co nanocapsules, bimetallic nanoparticles, and Co-polymer nanocomposites. These materials are applied in the field of catalysis, dielectrics, and renewable energy conversion devices.

Application

  • Rhenium (VII) compounds as inorganic precursors for the synthesis of organic reaction catalysts: Investigates the potential of Hexaamminecobalt(III) chloride as a replacement for commercial products in catalyzing organic reactions, highlighting its role in synthetic chemistry (K Leszczyńska-Sejda et al., 2019).
  • In situ formation of a molecular cobalt (iii)/AgCl photocatalyst for visible-light water oxidation: Discusses the synthesis and application of Hexaamminecobalt(III) chloride in forming a novel photocatalyst for water oxidation, a critical process in solar energy utilization (H Mogi et al., 2021).


pictograms

Health hazard

signalword

Danger

Hazard Classifications

Aquatic Chronic 4 - Carc. 2 - Resp. Sens. 1 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.


Michael G Poirier et al.
Journal of cellular biochemistry, 85(2), 422-434 (2002-04-12)
We show that the chromatin in mitotic chromosomes can be drastically overcompacted or unfolded by temporary shifts in ion concentrations. By locally 'microspraying' reactants from micron-size pipettes, while simultaneously monitoring the size of and tension in single chromosomes, we are
Z Gdaniec et al.
Biochemistry, 37(6), 1505-1512 (1998-03-04)
The ferritin IRE, a highly conserved (96-99% in vertebrates) mRNA translation regulatory element in animal mRNA, was studied by molecular modeling (using MC-SYM and DOCKING) and by NMR spectroscopy. Cobalt(III) hexammine was used to model hydrated Mg2+. IRE isoforms in
Yee Siew Choong et al.
Journal of molecular graphics & modelling, 29(6), 834-842 (2011-03-05)
The high typhoid incidence rate in developing and under-developed countries emphasizes the need for a rapid, affordable and accessible diagnostic test for effective therapy and disease management. TYPHIDOT®, a rapid dot enzyme immunoassay test for typhoid, was developed from the



Global Trade Item Number

SKUGTIN
481521-100G04061838147431
481521-25G04061832388670