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Merck
CN

517003

Iron(III) acetylacetonate

greener alternative

≥99.9% trace metals basis

Synonym(s):

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Linear Formula:
Fe(C5H7O2)3
CAS Number:
Molecular Weight:
353.17
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-853-5
Beilstein/REAXYS Number:
4157960
MDL number:
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Quality Level

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

180-182 °C (dec.) (lit.)

density

5.24 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

General description

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is an coordination compound that is used as a precursor for the synthesis of iron oxide nanoparticles and thin films, which are important in magnetic materials, catalysis, and electronic applications. Additionally, it is also used as a catalyst in various organic reactions, including polymerization processes and cross-coupling reactions.

Application

Iron(III) acetylacetonate can be used as:     
  • A iron precursor for the synthesis of Fe3O4/carbon composite fibers via forcespinning technique. This composite material used in the formation of high-performance anode materials for lithium-ion batteries.      
  • A precursor for the synthesis of iron-containing metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.   
  • An additive to enhance the efficiency of the N-hydroxyphthalimide (NHPI) catalyst in the oxidation of cumene.     
  • A solvent activation agent in the fabrication of polyamide membranes, which are used in reverse osmosis (RO) applications.     
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films. Iron (III) acetylacetonate may be used as a precursor for the synthesis of water-soluble magnetite nanoparticles, which may find applications in magnetic hyperthermia treatment.      
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Features and Benefits

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

纳米颗粒的溶剂热合成:从纳米电路、纳米光学电路到纳米磁学和生物技术应用。

High Purity Metalorganic Precursors for CPV Device Fabrication

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

View All Articles

Selective Detection of Iron (III) by Rhodamine-Modified Fe3O4 Nanoparticles.
Baodui, et al.
Angewandte Chemie (International Edition in English), 49.27, 4576-4579 (2010)
Studies of magnetite nanoparticles synthesized by thermal decomposition of iron (III) acetylacetonate in tri(ethylene glycol)
Maity D, et al.
Journal of magnetism and magnetic materials, 321(19), 3093-3098 (2009)
Arreerat Jiamprasertboon et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(48), 11337-11345 (2019-06-27)
Type I heterojunction films of α-Fe2 O3 /ZnO are reported here as a non-titania based photocatalyst, which shows remarkable enhancement in the photocatalytic properties towards stearic acid degradation under UVA-light exposure (λ=365 nm), with a quantum efficiency of ξ=4.42±1.54×10-4 molecules degraded/photon, which



Global Trade Item Number

SKUGTIN
517003-10G04061832541488
517003-50G04061832541495