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Merck
CN

520861

Potassium hexachloroplatinate(IV)

≥99.9% trace metals basis

Synonym(s):

Dipotassium hexachloroplatinate, Dipotassium platinum hexachloride, Platinic potassium chloride, Platinum potassium chloride, Potassium chloroplatinate, Potassium platinum(IV) chloride, Potassium platinum(IV) hexachloride

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About This Item

Linear Formula:
K2PtCl6
CAS Number:
Molecular Weight:
485.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
240-979-3
MDL number:
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Quality Level

assay

≥99.9% trace metals basis

composition

Pt, 38-41%

reaction suitability

reagent type: catalyst, core: platinum

mp

250 °C (dec.) (lit.)

SMILES string

[K+].[K+].Cl[Pt--](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.2K.Pt/h6*1H;;;/q;;;;;;2*+1;+4/p-6

InChI key

DPAIVKJGTXERIM-UHFFFAOYSA-H

Application

Potassium hexachloroplatinate(IV) can be used as a reactant to synthesize compounds such as chloropentaammineplatinum(IV), platinum triselenide, trans-dichloro(ethylenediamine-N,N′-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N′-di-3-propanoato)platinum(IV) complexes.


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Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



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Outer-sphere one-equivalent changes in the vanadium (II) reductions of hexachloroplatinate (IV) and chloropentaammineplatinum (IV).
Bakac A, et al.
Inorganic Chemistry, 14(10), 2540-2543 (1975)
Hongliang Li et al.
Nature nanotechnology, 13(5), 411-417 (2018-03-21)
Exploring the interaction between two neighbouring monomers has great potential to significantly raise the performance and deepen the mechanistic understanding of heterogeneous catalysis. Herein, we demonstrate that the synergetic interaction between neighbouring Pt monomers on MoS2 greatly enhanced the CO2
On the sulfides, selenides and tellurides of platinum.
Gr?nvold F, et al.
Acta Chemica Scandinavica, 14(9), 1879-1893 (1960)



Global Trade Item Number

SKUGTIN
520861-5G04061832547183
520861-1G04061835517909