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569593

4,4′-Dimethyl-2,2′-dipyridyl

99.5%, purified by sublimation

Synonym(s):

2,2′-Bi(γ-picoline), 4,4′-Dimethyl-2,2′-bipyridine

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About This Item

Empirical Formula (Hill Notation):
C12H12N2
CAS Number:
1134-35-6
Molecular Weight:
184.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24880510
EC Number:
214-483-2
Beilstein/REAXYS Number:
128995
MDL number:
MFCD00006441
Assay:
99.5%
Form:
solid
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Quality Level

100

assay

99.5%

form

solid

purified by

sublimation

mp

169-174 °C (lit.)

SMILES string

Cc1ccnc(c1)-c2cc(C)ccn2

InChI

1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3

InChI key

NBPGPQJFYXNFKN-UHFFFAOYSA-N

Application

4,4′-Dimethyl-2,2′-dipyridyl (dmbipy) may be used as a ligand in the synthesis of :
  • carbonato-bridged triangular trinuclear compounds and tetranuclear hydroxo-bridged compounds
  • dmbipy-copper bridged complexes, which show variation in crystal geometries, thermal and magnetic properties

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBQ0726V
MKBK0633V
MKBF8686V
MKBD2888
MKBD2887

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

Rapid Arylboronic Esters Synthesis by Ir(I)-Catalysis

Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

"Ferromagnetic trinuclear carbonato-bridged and tetranuclear hydroxo-bridged Cu (II) compounds with 4, 4'-dimethyl-2, 2'-bipyridine as ligand. X-ray structure, spectroscopy and magnetism"
Albada VAN, et al.
Inorgorganica Chimica Acta, 331(01), 208-215 (2002)
"Crystal Chemistry of the 4,4`-Dimethyl-2,2`bipyridine/Copper Bromide System"
Willett.DR, et al
Inorganic Chemistry, 40(17), 4342-4352 (2001)
Maxime Mourer et al.
Bioorganic & medicinal chemistry, 20(6), 2035-2041 (2012-03-01)
Various polycharged calix[4]arenes were assayed as anti-mycobacterial agents against Mycobacterium tuberculosis, H(37)Rv strain. The sulfonate, carboxylate and phosphonate anionic species displayed no activity. Cationic derivatives integrating four aminoethyl groups at the upper rim and two 6,6'-dimethyl-2,2'-bipyridyl- or 4,4'-dimethyl-2,2'-bithiazolyl subunits at
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Global Trade Item Number

SKUGTIN
569593-1G04061832597164
569593-5G04061833071526