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661384

2-Iodoxybenzoic acid

Name: 2-Iodoxybenzoic acid
Brand: ALDRICH

contains stabilizer, 45 wt. % (IBX)

Synonym(s):

SIBX, Stabilized IBX

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About This Item

Empirical Formula (Hill Notation):

C₇H₅IO₄

CAS Number:

61717-82-6

Molecular Weight:

280.02

NACRES:

NA.22

PubChem Substance ID:

24884529

UNSPSC Code:

12352005

MDL number:

MFCD02912492

Form:

solid

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Properties

form

solid

Quality Level

100

contains

stabilizer

reaction suitability

reagent type: oxidant

concentration

45 wt. % (IBX)

functional group

iodo

SMILES string

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

InChI key

CQMJEZQEVXQEJB-UHFFFAOYSA-N

Description

Application

Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.

Stabilized 2-Iodoxybenzoic Acid (SIBX)

A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.

Other Notes

The material is stabilized with benzoic acid and isophthalic acid

pictograms

GHS08,GHS05,GHS07

signalword

Danger

hcodes

H314,H335,H372

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Lungs, Respiratory system

supp_hazards

EUH044

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

pcodes

P260 - P271 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P314

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A stabilized formulation of IBX (SIBX) for safe oxidation reactions including a new oxidative demethylation of phenolic methyl aryl ethers.

Aurélie Ozanne et al.

Organic letters, 5(16), 2903-2906 (2003-08-02)

[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use

Lipophilization of Hydroxytyrosol-Enriched Fractions from Olea europaea L. Byproducts and Evaluation of the in Vitro Effects on a Model of Colorectal Cancer Cells.

Roberta Bernini et al.

Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)

A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate

Synthetic Communications, 37, 3493-3493 (2007)

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Global Trade Item Number

SKU	GTIN
CDS019650-100MG	04061828951345
661384-50G	04061832734101
661384-10G	04061832734088
661384-1G	04061832734095
661384-250G	04061833399484