677892
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
97%, solid
Synonym(s):
Cu(MeCN)4BF4, Copper(I) tetra(acetonitrile) tetrafluoroborate, Tetra(acetonitrile)copper(1+) tetrafluoroborate
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About This Item
Empirical Formula (Hill Notation):
C8H12BCuF4N4
CAS Number:
Molecular Weight:
314.56
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Tetrakis(acetonitrile)copper(I) tetrafluoroborate, 97%
Quality Level
assay
97%
form
solid
reaction suitability
core: copper, reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
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greener alternative category
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F
InChI
1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1
InChI key
YZGSKMIIVMCEFE-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application
Catalyst for greener oxidation of alcohols under aerobic conditions.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Paryzek, Z.; Martynow, J.
Journal of the Chemical Society. Perkin Transactions 1, 599-599 (1990)
Kevin M Gillespie et al.
The Journal of organic chemistry, 67(10), 3450-3458 (2002-05-11)
Racemic 2,2'-diamino-6,6'-dimethylbiphenyl is resolved using simulated moving bed chromatography, and the absolute configuration of the enantiomers is confirmed via the X-ray crystal structure of a derivative. The diamine is condensed with a range of aldehydes to give bidentate aldimine proligands
Bethell, D.; Jenkins, I. L.; Quan, P. M.
J. Chem. Soc. Perkin Trans. II, 1789-1789 (1985)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 677892-1G | 04061832748467 |
| 677892-5G | 04061832748474 |