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683213

Chiralyst P612

greener alternative

97%, Umicore, powder

Synonym(s):

Dichloro(p-cymene)ruthenium(II) dimer, Di(μ-chloro)dichlorobis(p-cymene)diruthenium(II), (p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

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About This Item

Linear Formula:
[Ru(p-cymene)Cl2]2
CAS Number:
52462-29-0
Molecular Weight:
612.39
UNSPSC Code:
12161600
PubChem Substance ID:
329760807
NACRES:
NA.22
MDL number:
MFCD00064793
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Product Name

Chiralyst P612, Umicore, 97%

Quality Level

100

assay

97%

form

powder

reaction suitability

core: ruthenium, reaction type: Cross Couplings, reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

247.0-250.0 °C (dec.) (lit.)

greener alternative category

Aligned

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

LAXRNWSASWOFOT-UHFFFAOYSA-J

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Hydrosilylation Catalysts
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

新产品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC5798
BCBZ8007
BCBV0070
BCBR4315V
MKBR8929V

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Articles

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)

Global Trade Item Number

SKUGTIN
683213-2G04061832755533
683213-500MG04061833540879