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731013

JackiePhos

Name: JackiePhos
Brand: ALDRICH

95%, solid

Synonym(s):

2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-3,6-dimethoxy -2′,4′,6′-triisopropyl-1,1′-biphenyl, Bis(3,5-bis(trifluoromethyl)phenyl)(2′,4′,6′- triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine

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About This Item

Empirical Formula (Hill Notation):

C₃₉H₃₇F₁₂O₂P

CAS Number:

1160861-60-8

Molecular Weight:

796.66

UNSPSC Code:

12352112

PubChem Substance ID:

329764613

NACRES:

NA.22

MDL number:

MFCD17015286

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Properties

Product Name

JackiePhos, 95%

Quality Level

100

product line

Buchwald Ligand

assay

95%

form

solid

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation

mp

186-190 °C

functional group

phosphine

SMILES string

COc1ccc(OC)c(c1P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F)-c4c(cc(cc4C(C)C)C(C)C)C(C)C

InChI

1S/C39H37F12O2P/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51/h9-21H,1-8H3

InChI key

KYTUFIMHJNRPLC-UHFFFAOYSA-N

Description

Application

JackiePhos is a Buchwald′s phosphine ligand which can be used for the:

glycosyl cross-coupling reaction of diaryliodonium triflates with anomeric stannanes to synthesize C-glycosides.
synthesis of gold-based catalyst complexes such as [Au(CH₃CN)(JackiePhos)][SbF₆] and [(JackiePhos)AuCl.
acylation of alkylcarbastannatranes.
synthesis of cyclic guanidines or cyclic ureas bearing dialkylaminomethyl groups in combination with Pd(acac)₂ as a catalyst.

Catalyst for N-Arylation reactions

Buchwald Phosphine Ligands for chemical Synthesis

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Global Trade Item Number

SKU	GTIN
731013-1G	04061826653326
731013-100MG	04061833240120
731013-250MG	04061833240137