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Merck
CN

731269

2-Phenyl-2-propyl benzodithioate

99% (HPLC)

Synonym(s):

2-Phenylpro-2-yl dithiobenzoate, Benzenecarbodithioic acid 1-methyl-1phenylethyl ester, Cumyl dithiobenzoate

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About This Item

Empirical Formula (Hill Notation):
C16H16S2
CAS Number:
Molecular Weight:
272.43
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

99% (HPLC)

form

solid

density

1.125 g/mL at 25 °C

SMILES string

CC(C)(SC(=S)c1ccccc1)c2ccccc2

InChI

1S/C16H16S2/c1-16(2,14-11-7-4-8-12-14)18-15(17)13-9-5-3-6-10-13/h3-12H,1-2H3

InChI key

KOBJYYDWSKDEGY-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylates/methacrylamides, and to a lesser extent acrylates/acrylamides and styrenes; Chain Transfer Agent (CTA)


pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

219.9 °F

flash_point_c

104.4 °C



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Protocols

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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Articles

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

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Fatemeh Karimi et al.
Biomaterials, 187, 81-92 (2018-10-12)
Biomaterials are a powerful platform for directing cellular behaviour. Herein, we employed a biomimetic strategy to synthesize a low-fouling polymer functionalized with nano-scale clusters of ligands that bind both integrin and syndecan-4 receptors, as both receptor types are critical in
Meijie Wang et al.
Journal of biomaterials science. Polymer edition, 31(7), 849-868 (2020-02-06)
In this article, we introduce a pH-responsive charge-reversible and photo-crosslinkable polymer nanoparticle. It is prepared via typical self-assembly from a block copolymer poly((7-(4-vinyl-benzyloxyl)-4-methylcoumarin)-co-acrylicacid)-b-poly((2-dimethylamino) ethyl methacrylate)-co-styrene) (P(VBMC-co-AA)-b-P(DMAEMA-co-St)), whose two blocks have different ionizable moieties. In an aqueous solution of pH ≤
Assad U Khan et al.
ACS nano, 13(4), 4255-4266 (2019-03-26)
State-of-the-art commercial light-reflecting glass is coated with a metalized film to decrease the transmittance of electromagnetic waves. In addition to the cost of the metalized film, one major limitation of such light-reflecting glass is the lack of spectral selectivity over



Global Trade Item Number

SKUGTIN
731269-5G04061832978246
731269-1G04061826280652