754730
Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate
97%
Synonym(s):
Ru(bpy)3(PF6)2, Ruthenium-tris(2,2′-bipyridyl) dihexafluorophosphate
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About This Item
Empirical Formula (Hill Notation):
C30H24F12N6P2Ru
CAS Number:
Molecular Weight:
859.55
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
description
Emissive Layer
Quality Level
assay
97%
form
solid
reaction suitability
core: ruthenium, reaction type: Photocatalysis, reagent type: catalyst
impurities
(Material is not fluorescence active.)
mp
>300 °C
photocatalyst activation
425 nm
absorption
13,400 at 456 nm, 80,000 at 291 nm
SMILES string
[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6
InChI
1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2
InChI key
KLDYQWXVZLHTKT-UHFFFAOYSA-N
General description
Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate (Ru(bpy)3(PF6)2) is a conducting polymer that is majorly used as an active layer in electrochemical devices. It facilitates the formation of highly efficient and low voltage devices. It shows an external quantum efficiency of 0.35 and 400 cd/m2 at 3V.
Application
Ru(bpy)3(PF6)2 may be used as a conjugating polymer in the development of light emitting electrochemical cell based devices such as light emitting diodes (LEDs). It is also used as a high-efficiency triplet emitter for OLED/Sensor research.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
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Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Wesley R Browne et al.
Journal of the American Chemical Society, 125(7), 1706-1707 (2003-02-13)
The excited-state properties of the transition metal complexes tris(2,2'-bipyridine) ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) are examined using picosecond time-resolved luminescence spectroscopy. For both complexes, direct observation of a short-lived high-energy emission with a lifetime of less than 4 ps is reported.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 754730-1G | 04061832908458 |