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798835

[Ru(phd)3](PF6)2

Synonym(s):

Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)

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About This Item

Empirical Formula (Hill Notation):
C36H18F12N6O6P2Ru
CAS Number:
184023-77-6
Molecular Weight:
1021.56
UNSPSC Code:
12352202
PubChem Substance ID:
329768673
NACRES:
NA.22
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form

powder

reaction suitability

core: ruthenium, reagent type: catalyst

SMILES string

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]

InChI

1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2

InChI key

LGAOGZFZNIEFHF-UHFFFAOYSA-N

Application

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)3](PF6)2 is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Legal Information

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCD8984
MKBW7472V

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Related Content

Stahl Group – Professor Product Portal

he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.

Global Trade Item Number

SKUGTIN
798835-100MG04061833232286