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81080

Chloroplatinic acid hydrate

~38% Pt, powder

Synonym(s):

Hexachloroplatinic(IV) acid hydrate, Hydrogen hexachloroplatinate(IV) hydrate, Platinic chloride hydrate

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About This Item

Linear Formula:
H2PtCl6 · xH2O
CAS Number:
26023-84-7
Molecular Weight:
409.81 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
57652846
UNSPSC Code:
12161600
EC Number:
241-010-7
MDL number:
MFCD00149909
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Product Name

Chloroplatinic acid hydrate, ~38% Pt basis

Quality Level

100

form

powder

reaction suitability

core: platinum, reagent type: catalyst

concentration

~38% Pt

mp

60 °C (lit.)

density

2.43 g/mL at 25 °C (lit.)

SMILES string

O.Cl.Cl.Cl[Pt](Cl)(Cl)Cl

InChI

1S/6ClH.H2O.Pt/h6*1H;1H2;/q;;;;;;;+4/p-4

InChI key

SLIOYUPLNYLSSR-UHFFFAOYSA-J

Application

Catalyst for:
  • Reduction of carboxamides with hydrosilanes
  • Hydrosilylation of siloxanes
  • Dehydrocoupling polycondensation reactions
  • Hydrolysis of trichlorosilanes
Hydrosilylation Catalysts

Preparation Note

1. Hygroscopic material, always handle in a glove bag or a glove box filled with dry inert gas
2. Recommended for one time use to prevent water absorption and degradation. If necessary, once opened, repack and seal under dry inert gas.
3. Store with care. Prevent from light. Always store in well-sealed containers in a dry inert atmosphere. Recommended to store containers in a secondary desiccator with desiccant in a dry inert atmosphere.
Packaged under dry Nitrogen gas

Other Notes

Catalyst for the hydrosilylation of olefins

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG8361
BCCG3591
BCCG0979
BCCF4646
BCCF2842

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J.L. Speier
Adv. Organomet. Chem., 17, 407-407 (1979)
Lewis, L. N.; Sy, K. G. et al.
Organometallics, 10, 3750-3750 (1991)
Toal, S. J.; et al.
Organometallics, 24, 3081-3081 (2005)
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Global Trade Item Number

SKUGTIN
81080-1G04061835555543
81080-5G04061835555550