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Merck
CN

82320

(±)-Propylene oxide

puriss. p.a., ≥99.5% (GC)

Synonym(s):

(±)-Methyloxirane, 1,2-Epoxypropane

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About This Item

Empirical Formula (Hill Notation):
C3H6O
CAS Number:
Molecular Weight:
58.08
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
200-879-2
Beilstein/REAXYS Number:
79763
MDL number:
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vapor density

2 (vs air)

Quality Level

vapor pressure

29.43 psi ( 55 °C), 8.59 psi ( 20 °C)

grade

puriss. p.a.

assay

≥99.5% (GC)

form

liquid

autoignition temp.

1378 °F

expl. lim.

37 %

impurities

≤0.1% water

evapn. residue

≤0.005%

refractive index

n20/D 1.366

bp

34 °C (lit.)

mp

−112 °C (lit.)

density

0.83 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg

shipped in

wet ice

storage temp.

2-8°C

SMILES string

CC1CO1

InChI

1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3

InChI key

GOOHAUXETOMSMM-UHFFFAOYSA-N

General description

(±)-Propylene oxide (PPO) belongs to the class of monomers known as epoxides or oxiranes. It is used as a raw material in the preparation n of polyurethane foam and polyether polyols, which are used in the production of polyurethane elastomers, polyurethane plastics, adhesives, sealants, and coatings. These materials find applications in industries such as automotive, construction, electronics, and textiles. PPO-based polymers possess flexibility and elasticity as inherent properties, making them well-suited for applications that demand materials with excellent resilience, stretchability, and impact resistance. Additionally, PPO-derived polymers are biocompatible, which makes them suitable for applications in various fields such as biomedical engineering, drug delivery, and tissue engineering.

Application

Propylene oxide can be used as a starting material to synthesize:
  • Poly(3-hydroxybutyrate), a biodegradable and biocompatible polyester, by carbonylative polymerization.
  • Poly (propylene-ram-ε-caprolactone carbonate) (PPCL) and poly (propylene carbonate) (PPC), which are applicable as drug carriers.
Propylene oxide may be used in the production of polyether polyols, propylene glycols, propylene glycol ethers.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-36.4 °F - Equilibrium method

flash_point_c

-38 °C - Equilibrium method

ppe

Faceshields, Gloves, Goggles

Regulatory Information

危险化学品

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Josep Casamada Ribot et al.
Chemical communications (Cambridge, England), 46(37), 6971-6973 (2010-08-24)
The aqueous gelation of a quaternary ammonium oligo(propylene oxide)-based ionic liquid yields ion gels with a reverse thermoresponsive behavior (i.e., mechanical moduli and viscosity increase with temperature) and enhanced ionic conductivities.
Aude Bouchet et al.
The Journal of organic chemistry, 76(10), 4178-4181 (2011-04-08)
ECD and NMR experiments show that the complexation of propylene oxide (PrO) within the cavity of an enantiopure water-soluble cryptophane 1 in NaOH solution is enantioselective and that the (R)-PrO@PP-1 diastereomer is more stable than the (S)-PrO@PP-1 diastereomer with a
Denis Merlet et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 209(2), 315-322 (2011-02-25)
The application of the G-SERFph pulse sequence is presented on enantiomeric mixtures dissolved in a chiral liquid crystal. It aims at editing, within one single 2D spectrum, every proton coupling which is experienced by a given proton site in the



Global Trade Item Number

SKUGTIN
82320-1L04061833005040
82320-250ML04061838339423