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Merck
CN

86885

Tetrabutylammonium perchlorate

≥95.0% (T)

Synonym(s):

TBAP

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(ClO4)
CAS Number:
Molecular Weight:
341.91
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-655-5
Beilstein/REAXYS Number:
3579274
MDL number:
Assay:
≥95.0% (T)
Form:
powder
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Quality Level

assay

≥95.0% (T)

form

powder

reaction suitability

core: ammonium, reagent type: oxidant

functional group

amine

SMILES string

[O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

KBLZDCFTQSIIOH-UHFFFAOYSA-M

Application

Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis.


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pictograms

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signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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ESCA studies of phase-transfer catalysts in solution: ion pairing and surface activity
Moberg R, et al.
Journal of the American Chemical Society, 113(10), 3663-3667 (1991)
David Balcells et al.
Dalton transactions (Cambridge, England : 2003), (30)(30), 5989-6000 (2009-07-23)
Experimental studies have shown that the C-H oxidation of Ibuprofen and methylcyclohexane acetic acid can be carried out with high selectivities using [(terpy')Mn(OH(2))(mu-O)(2)Mn(OH(2))(terpy')](3+) as catalyst, where terpy' is a terpyridine ligand functionalized with a phenylene linker and a Kemp's triacid
Atanu Jana et al.
Dalton transactions (Cambridge, England : 2003), 44(1), 359-367 (2014-11-11)
A novel electron rich, tetrathiafulvalene fused zinc porphyrin, (TTF)4PZn, has been newly synthesized and characterized using spectral and electrochemical methods. In spite of the presence of eight t-butyl groups, (TTF)4PZn exhibited appreciable aggregation in solution. Scanning electron microscopic (SEM) imaging



Global Trade Item Number

SKUGTIN
86885-100G04061835555635
86885-25G04061835521470