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900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

Name: 9-Mesityl-3,6-di-<I>tert</I>-butyl-10-phenylacridinium tetrafluoroborate
Brand: ALDRICH

≥95%, powder or crystals

Synonym(s):

3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):

C₃₆H₄₀BF₄N

CAS Number:

1810004-87-5

Molecular Weight:

573.51

MDL number:

MFCD31381908

UNSPSC Code:

12352005

NACRES:

NA.22

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Properties

Product Name

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate, ≥95%

Quality Level

100

assay

≥95%

form

powder or crystals

reaction suitability

core: acridinium, reagent type: catalyst
reaction type: Photocatalysis

mp

277.2 °C

photocatalyst activation

455 nm

SMILES string

[F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C

InChI

InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1

InChI key

YUNSHKYOOCWQRB-UHFFFAOYSA-N

Description

Application

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Site-selective arene C-H amination via photoredox catalysis

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Global Trade Item Number

SKU	GTIN
900421-100MG	04061833244531