909335
2-(2,4-Difluorophenyl)-5-(trifluoromethyl)pyridine
≥95%, powder or crystals
Synonym(s):
dFCF3ppy
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About This Item
Empirical Formula (Hill Notation):
C12H6F5N
CAS Number:
Molecular Weight:
259.17
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Assay:
≥95%
Form:
powder or crystals
Product Name
2-(2,4-Difluorophenyl)-5-(trifluoromethyl)pyridine, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
mp
59-64 °C
SMILES string
FC(F)(F)c1cnc(cc1)c2c(cc(cc2)F)F
InChI
1S/C12H6F5N/c13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17/h1-6H
InChI key
FMKQPMDFNYNYAG-UHFFFAOYSA-N
Application
2-(2,4-Difluorophenyl)-5-(trifluoromethyl)pyridine is a ligand used for the preparation of Ir(III) photocatalysts.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Kazimer L Skubi et al.
Journal of the American Chemical Society, 139(47), 17186-17192 (2017-11-01)
Stereochemical control of electronically excited states is a long-standing challenge in photochemical synthesis, and few catalytic systems that produce high enantioselectivities in triplet-state photoreactions are known. We report herein an exceptionally effective chiral photocatalyst that recruits prochiral quinolones using a
Thomas Rossolini et al.
Organic letters, 20(21), 6794-6798 (2018-10-24)
A visible-light-mediated photocatalytic umpolung synthesis of 1,3-diamines from in situ-generated imines and dehydroalanine derivatives is described. Pivoting on a key nucleophilic addition of photocatalytically generated α-amino radicals to electron-deficient alkenes, this three-component coupling reaction affords 1,3-diamines efficiently and diastereoselectively. The
Timothy M Monos et al.
Science (New York, N.Y.), 361(6409), 1369-1373 (2018-09-29)
Alkene aminoarylation with a single, bifunctional reagent is a concise synthetic strategy. We report a catalytic protocol for the addition of arylsulfonylacetamides across electron-rich alkenes with complete anti-Markovnikov regioselectivity and excellent diastereoselectivity to provide 2,2-diarylethylamines. In this process, single-electron alkene