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910228

1,3,5,7-Tetramethyl-2,4,8-trioxo-6-(2-bromophenyl)-6-phosphaadamantane

≥95%

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About This Item

Empirical Formula (Hill Notation):
C16H20BrO3P
CAS Number:
1236039-82-9
Molecular Weight:
371.21
UNSPSC Code:
12352200
Assay:
≥95%
Form:
powder or crystals
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assay

≥95%

form

powder or crystals

reaction suitability

reagent type: ligand

mp

151 °C

functional group

phosphine

Application

1,3,5,7-Tetramethyl-2,4,8-trioxo-6-(2-bromophenyl)-6-phosphaadamantane is a precursor to PAd-Dalphos (900593) and related phosphine ligands developed by the Stradiotto lab.

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Lot/Batch Number
SHBN6134
SHBN0646

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Christopher M Lavoie et al.
Nature communications, 7, 11073-11073 (2016-03-24)
Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical industry, for the synthesis of (hetero)aniline derivatives. However, the cost and relative scarcity of palladium provides motivation for the development of alternative, more