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Merck
CN

921025

Palladium(II) acetylacetonate

≥99.9% trace metals basis

Synonym(s):

Palladium(II) 2,4-pentanedionate, Pd(acac)2

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About This Item

Linear Formula:
Pd(C5H7O2)2
CAS Number:
Molecular Weight:
304.64
NACRES:
NA.23
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4136188
MDL number:
Assay:
≥99.9% trace metals basis
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Quality Level

assay

≥99.9% trace metals basis

reaction suitability

core: palladium

mp

200-251 °C (dec.)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES string

CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

JKDRQYIYVJVOPF-FDGPNNRMSA-L

Application

Palladium(II) 2,4-pentanedionate can be used to synthesize palladium(II) complexes applicable in common cross-coupling reactions like Suzuki, Heck and Buchwald-Hartwig coupling. As a palladium precursor, it can be used to synthesize hollow Pd/Pt single-crystalline nanocubes with enhanced electrocatalytic activity due to increased surface area. The surface modification of TiO2 using Pd(acac)2 as a metal-organic precursor has enhanced its photocatalytic activity under UV irradiation. Pd(acac)2 can also be used to develop bimetallic alloy NP catalysts applicable in formic acid dehydrogenation.


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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Global Trade Item Number

SKUGTIN
921025-1G04065266624724
921025-5G04065266624731