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Merck
CN

931578

Ruthenium(III) chloride hydrate

≥99.9% trace metals basis

Synonym(s):

Ruthenium trichloride, Trichlororuthenium hydrate

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About This Item

Linear Formula:
RuCl3 · xH2O
CAS Number:
Molecular Weight:
207.43 (anhydrous basis)
UNSPSC Code:
12352302
NACRES:
NA.21
MDL number:
Assay:
≥99.9% trace metals basis
Form:
powder
Solubility:
acetone: soluble ((lit.)), ethanol: soluble, water: soluble
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Quality Level

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: ruthenium

impurities

≤1000.0 ppm (trace metals analysis)

solubility

acetone: soluble ((lit.)), ethanol: soluble, water: soluble

density

3.11 g/cm3

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES string

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

General description

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

Application

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Discover the ways in which high-purity metal salts improve the selectivity, yields, and catalytic efficacy of organic synthesis reactions.


Fabing Su et al.
Journal of the American Chemical Society, 129(46), 14213-14223 (2007-11-02)
We report here a thermal reduction method for preparing Ru catalysts supported on a carbon substrate. Mesoporous SBA-15 silica, surface-carbon-coated SBA-15, templated mesoporous carbon, activated carbon, and carbon black with different pore structures and compositions were employed as catalyst supports



Global Trade Item Number

SKUGTIN
931578-10G04065269000822
931578-2G04065269000839