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About This Item
Linear Formula:
H2NC6H4OH
CAS Number:
Molecular Weight:
109.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-431-1
Beilstein/REAXYS Number:
606075
MDL number:
Assay:
99%
Form:
powder
Quality Level
assay
99%
form
powder
mp
170-175 °C (lit.)
SMILES string
Nc1ccccc1O
InChI
1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2
InChI key
CDAWCLOXVUBKRW-UHFFFAOYSA-N
Application
2-Aminophenol can be used in the synthesis of:
- 2-Oxazolidinone derivatives by reacting with β-aminoalcohols in presence of Pd/C-I2 as a catalyst via oxidative cyclocarbonylation.
- Schiff base transition metal(II) complexes with salicylidene-4-aminoantipyrine.
- 2-Arylbenzoxazoles with aldehydes catalyzed by activated carbon in presence of oxygen atmosphere.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
334.4 °F - closed cup
flash_point_c
168 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Bifu Liu et al.
Chemical communications (Cambridge, England), 48(93), 11446-11448 (2012-10-23)
A robust route to 4-amine-benzo[b][1,4]oxazepines relying upon a palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides has been developed. This chemistry presumably proceeds through the migratory insertion of isocyanides into the vinyl-palladium intermediate as a key step.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| A71301-5G | 04061832883380 |
| A71301-100G | 04061833383612 |
| A71301-500G | 04061833383629 |

