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Merck
CN

B35407

2,2′-Biquinoline

98%

Synonym(s):

2,2′-Diquinolyl, Cuproin

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About This Item

Empirical Formula (Hill Notation):
C18H12N2
CAS Number:
Molecular Weight:
256.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-357-5
Beilstein/REAXYS Number:
187259
MDL number:
Assay:
98%
Form:
powder
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Quality Level

assay

98%

form

powder

mp

192-195 °C (lit.)

SMILES string

c1ccc2nc(ccc2c1)-c3ccc4ccccc4n3

InChI

1S/C18H12N2/c1-3-7-15-13(5-1)9-11-17(19-15)18-12-10-14-6-2-4-8-16(14)20-18/h1-12H

InChI key

WPTCSQBWLUUYDV-UHFFFAOYSA-N

Application

2,2′-Biquinoline can be utilized as a ligand in the synthesis of heteroleptic Cu(I) complexes for light-emitting diodes(LED) and cationic iridium(III) complexes as phosphorescent dyes for live-cell imaging.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Cationic iridium (III) complexes with tunable emission color as phosphorescent dyes for live cell imaging
Zhao Q, et al.
Organometallics, 29(5), 1085-1091 (2010)
Leszek Pazderski et al.
Magnetic resonance in chemistry : MRC, 45(12), 1059-1071 (2007-11-30)
1H, 13C, and 15N NMR studies of platinide(II) (M=Pd, Pt) chloride complexes with quinolines (L=quinoline-quin, or isoquinoline-isoquin; LL=2,2'-biquinoline-bquin), having the general formulae trans-/cis-[ML2Cl2] and [M(LL)Cl2], were performed and the respective chemical shifts (delta1H, delta13C, delta15N) reported. 1H coordination shifts of
Chun-fen Zhang et al.
Guang pu xue yu guang pu fen xi = Guang pu, 23(2), 217-220 (2003-09-10)
Steady-state fluorescence and anisotropy measurements have been used to investigate the interaction of 2,2'-biquinoline (BQ) and 1,1'-(methylenedi-1,4-phenylene)bismaleimide (MDP-BMI) with alpha-, beta-, and gamma-cyclodextrins (CDs). It was found that the reaction patterns between fluorescence molecules and CDs are remarkably different. They



Global Trade Item Number

SKUGTIN
B35407-5G04061833349496
B35407-1G04061833428245