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Merck
CN

F300

Iron(III) acetylacetonate

greener alternative

97%

Synonym(s):

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Linear Formula:
Fe(C5H7O2)3
CAS Number:
Molecular Weight:
353.17
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-853-5
Beilstein/REAXYS Number:
4157960
MDL number:
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Quality Level

assay

97%

form

powder

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

180-182 °C (dec.) (lit.)

density

5.24 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

General description

Iron(III) acetylacetonate is a reddish crystalline solid that dissolves easily in organic solvents, making it suitable for solution-based processing. Its good thermal stability and controlled decomposition make it ideal as a precursor for techniques like Chemical Vapor Deposition (CVD) and Atomic Layer Deposition (ALD), which are used for fabricating iron-containing thin films, such as iron oxide (Fe₂O₃), used in sensors, catalysis, and electronics.We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) acetylacetonate can be used as:
  • Precursor for the synthesis of magnetite nanoparticles via solvothermal method with applications in medical field, nanocomposite preparations, and thin film depositions and biomedical applications.
  • Precursor in the synthesis of iron oxide nanoparticles like (magnetite, maghemite and wustite via thermal decomposition method.
  • These nanoparticles have applications in magnetic materials, drug delivery, biosensing and as catalysts.
  • Catalyst or a precursor for supported catalysts in oxidation and polymerization reactions, particularly in the development of advanced catalytic materials.
MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Features and Benefits

Iron(III) acetylacetonate (97%) has diverse applications in catalysis, nanoparticle synthesis, pigment production, research, and electrochemical devices. The purity, concentration, and significantly influence its performance and effectiveness in these applications.


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pictograms

CorrosionExclamation mark

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

金属有机骨架(MOF)是一类相对较新的多孔晶体材料,具有广泛的应用范围。MOF由充当接合处的金属离子或簇组成,并由多向有机配体所结合,而其在网络结构中作为接头。

Prof. Randal Lee discusses iron oxide magnetic nanospheres and nanocubes design considerations for biosensing applications.

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.


Wei Zhang et al.
Journal of environmental sciences (China), 86, 213-224 (2019-12-04)
We investigated the adsorption performance of five Fe-based MOFs (Fe-BTC, MIL-100(Fe), MIL-101(Fe), MIL-53(Fe) and MIL-88C(Fe)) for removal of antimonite (Sb(III)) and antimonate (Sb(V)) from water. Among these MOFs, MIL-101(Fe) exhibited the best adsorption capacities for both Sb(III) and Sb(V) (151.8
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Ruth Rodríguez-Ramos et al.
Chemosphere, 236, 124377-124377 (2019-09-25)
In this study, the application of different nanomaterials as dispersants in matrix solid phase dispersion has been evaluated for the extraction of fifteen phthalates from different environmental samples prior to their separation and quantification by ultra-high performance liquid chromatography coupled



Global Trade Item Number

SKUGTIN
690872-10G04061832765204
690872-100G04061833314906
690872-500G04061833499849
F300-100G04061833613399
F300-25G04061833613405
F300-500G04061833613412