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Merck
CN

1.05679

Lithium chloride

for analysis EMSURE® ACS,Reag. Ph Eur

Synonym(s):

Lithium chloride

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About This Item

Empirical Formula (Hill Notation):
ClLi
CAS Number:
Molecular Weight:
42.39
UNSPSC Code:
12352302
EC Index Number:
231-212-3
NACRES:
NA.21
MDL number:
Assay:
≥99% (LiCl basis, silver nitrate titration)
Grade:
ACS reagent
Form:
solid
Solubility:
832 g/L
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grade

ACS reagent

Quality Level

agency

reag. Ph. Eur.

vapor pressure

1.33 hPa ( 547 °C)

product line

EMSURE®

assay

≥99% (LiCl basis, silver nitrate titration)

form

solid

potency

526 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rat)

impurities

≤0.008 meq/g Total of alkali, ≤0.01% Insoluble matter

loss

≤1% loss on drying, 130 °C

pH

6 (20 °C, 50 g/L in H2O)

bp

1360 °C/1013 hPa

mp

614 °C

solubility

832 g/L

density

2.07 g/cm3 at 20 °C

bulk density

530 kg/m3

anion traces

nitrate (NO3-): ≤0.001%, sulfate (SO42-): ≤0.005%

cation traces

Ba: ≤0.002%, Ca: ≤0.005%, Fe: ≤0.0005%, K: ≤0.01%, Mg: ≤0.005%, Na: ≤0.02%, heavy metals (as Pb): ≤0.0005%

storage temp.

2-30°C

SMILES string

[Li+].[Cl-]

InChI

1S/ClH.Li/h1H;/q;+1/p-1

InChI key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

Application


  • Stereocontrolled synthesis of syn-beta-Hydroxy-alpha-amino acids by direct aldolization of pseudoephenamine glycinamide.: Lithium chloride is employed in the stereocontrolled synthesis of syn-beta-Hydroxy-alpha-amino acids, highlighting its role in advanced synthetic chemistry techniques. This research provides insights into chemical synthesis and the development of complex organic compounds, relevant for chemists focusing on synthetic methodologies (Seiple et al., 2014).

Analysis Note

Assay (argentometric, LiCl): ≥ 99 %
Insoluble matter: ≤ 0.01 %
Nitrate (NO₃): ≤ 0.001 %
Sulfate (SO₄): ≤ 0.005 %
Heavy metals (as Pb): ≤ 0.0005 %
Ba (Barium): ≤ 0.002 %
Ca (Calcium): ≤ 0.005 %
Fe (Iron): ≤ 0.0005 %
K (Potassium): ≤ 0.01 %
Mg (Magnesium): ≤ 0.005 %
Na (Sodium): ≤ 0.02 %
Total of alkali: ≤ 0.008 meq/g
Loss on drying (130 °C): ≤ 1.0 %

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



Certificates of Analysis (COA)

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Global Trade Item Number

SKUGTIN
D174203-100ML04061833560594
D174203-25ML04061837018343
W506206-SAMPLE04061837847028
W506206-1KG04061837847011
803770000504022536383132
803770025004022536383149
803770100004022536383156
105679010004022536066998
105679025004022536067001
105679901204027269964528
105679905004022536067032