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Merck
CN

08748

Triethylsulfonium bis(trifluoromethylsulfonyl)imide

for electrochemistry, ≥95.0% (qNMR)

Synonym(s):

[SEt3] NTf2

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About This Item

Empirical Formula (Hill Notation):
C8H15F6NO4S3
CAS Number:
Molecular Weight:
399.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

≥95.0% (qNMR)

form

liquid

impurities

≤200 ppm water

conductivity

~6.0 mS/cm

mp

-35.5 °C

anion traces

bromide (Br-): ≤10 mg/kg, chloride (Cl-): ≤10 mg/kg, fluoride (F-): ≤10 mg/kg, nitrate (NO3-): ≤10 mg/kg

functional group

fluoro, thioether

SMILES string

CC[S+](CC)CC.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H15S.C2F6NO4S2/c1-4-7(5-2)6-3;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H2,1-3H3;/q+1;-1

InChI key

BLODSRKENWXTLO-UHFFFAOYSA-N

General description

Symmetric and aliphatic trialkylsulfonium cations form room temperature molten salts with bis(trifluoromethylsulfonyl)imide.

Application

Triethylsulfonium bis(trifluoromethylsulfonyl)imide is a room-temperature ionic liquid (RTIL ) that can be used:
  • As an electrolyte in electrochemical double-layer supercapacitors.
  • As a model ionic liquid used in the studies of structure effect of ions on electrochemical windows (EWs).
  • As a component of the gel polymer electrolyte, which is used in the construction of symmetrical electrical-double layer capacitors.
  • As an electrolyte in the in-plane supercapacitor devices.



pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Articles

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.


Matsumoto, H., et al.
Chemistry Letters (Jpn), 29, 1430-1430 (2000)
Nanocomposites of graphene nanosheets/multiwalled carbon nanotubes as electrodes for in-plane supercapacitors
Trigueiro JPC, et al.
Electrochimica Acta, 187(1), 312-322 (2016)
Investigating the electrochemical windows of ionic liquids.
Hayyan M, et al.
Journal of Industrial and Engineering Chemistry, 19(1), 106-112 (2013)



Global Trade Item Number

SKUGTIN
D134406-5G04061835282173
D134406-1G04061835282159
D134406-25G04061835282166
08748-50G-F04061838652836
08748-5G-F04061833458587