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234672

2,2′:6′,2′′-Terpyridine

Name: 2,2&#8242;:6&#8242;,2&#8242;&#8242;-Terpyridine
Brand: SIAL

98%, solid

Synonym(s):

α,α′,α″-Tripyridyl, 2,6-Di(2-pyridyl)pyridine

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About This Item

Empirical Formula (Hill Notation):

C₁₅H₁₁N₃

CAS Number:

1148-79-4

Molecular Weight:

233.27

NACRES:

NA.21

PubChem Substance ID:

57648035

UNSPSC Code:

12352100

EC Number:

214-559-5

MDL number:

MFCD00006213

Beilstein/REAXYS Number:

11199

Assay:

98%

Form:

solid

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Properties

Product Name

2,2′:6′,2′′-Terpyridine, 98%

Quality Level

200

assay

98%

form

solid

mp

89-91 °C (lit.)

SMILES string

c1ccc(nc1)-c2cccc(n2)-c3ccccn3

InChI

1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H

InChI key

DRGAZIDRYFYHIJ-UHFFFAOYSA-N

Description

General description

2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps, starting with 2-acetylpyridine. It coordinates with metal centers to form complexes. It is also utilized in the synthesis of chiral derivatives for asymmetric catalysis.

Application

Due to the presence of three near-coplanar nitrogen donor atoms, 2,2′:6′,2′′;-terpyridine may be used as a metal-binding domain to form metallo-supramolecular structures.

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pictograms

GHS06,GHS05

signalword

Danger

hcodes

H300 + H310,H315,H318,H335

pcodes

P261 - P262 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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2, 2?: 6?, 2 ?-Terpyridines: From chemical obscurity to common supramolecular motifs

Constable EC

Chemical Society Reviews, 36(2), 246-253 (2007)

An improved, two-step synthesis of 2, 2?: 6?, 2 ?-terpyridine

Jameson DL & Guise LE

Tetrahedron Letters, 32(18), 1999-2002 (1991)

New functional polymers and materials based on 2, 2': 6', 2 ?-terpyridine metal complexes.

Andres PR and Schubert US.

Advanced Materials, 16(13), 1043-1068 (2004)

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Global Trade Item Number

SKU	GTIN
234672-1G	04061838784629
234672-250MG	04061832747590
234672-5G	04061838784636