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Merck
CN

242586

Diphenylamine

ACS reagent grade, ≥99%

Synonym(s):

DPA

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About This Item

Linear Formula:
(C6H5)2NH
CAS Number:
Molecular Weight:
169.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
204-539-4
MDL number:
Beilstein/REAXYS Number:
508755
Assay:
≥99%
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Product Name

Diphenylamine, ACS reagent, ≥99%

grade

ACS reagent

Quality Level

vapor density

5.82 (vs air)

vapor pressure

1 mmHg ( 108 °C)

assay

≥99%

autoignition temp.

1175 °F

ign. residue

≤0.03%

bp

302 °C (lit.)

mp

50-53 °C (lit.)

solubility

alcohol: passes test

anion traces

nitrate (NO3-): passes test

suitability

passes test for sensitivity to nitrate

SMILES string

N(c1ccccc1)c2ccccc2

InChI

1S/C12H11N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

InChI key

DMBHHRLKUKUOEG-UHFFFAOYSA-N

Gene Information

human ... UGT1A4(54657)

Application

Diphenylamine can undergo palladium-catalyzed intramolecular cyclization to form carbazole. It may also be used as a starting material in the synthesis of triphenylamine.
Diphenylamine may be used in the preparation of diphenylamine reagent, which is employed for the quantitative estimation of nucleic acid (DNA) from various biological sources by colorimetric method.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

target_organs

Kidney,Liver,spleen

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Triphenylamine
Hager FD
Organic Syntheses, 8(116), 116-116 (1928)
An improved diphenylamine method for the estimation of deoxyribonucleic acid.
Giles KW and Myers A.
Nature, 206(4979), 93-93 (1965)
A study of the conditions and mechanism of the diphenylamine reaction for the colorimetric estimation of deoxyribonucleic acid.
K BURTON
The Biochemical journal, 62(2), 315-323 (1956-02-01)



Global Trade Item Number

SKUGTIN
PH017019-1G04054839945328
242586-100G04061835365470
242586-500G04061825589497
242586-5G04061835365487