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Merck
CN

254002

Pyrogallol

ACS reagent grade, solid

Synonym(s):

1,2,3-Trihydroxybenzene, 2,3-Dihydroxyphenol, Pyrogallic acid

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About This Item

Linear Formula:
C6H3(OH)3
CAS Number:
Molecular Weight:
126.11
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
EC Number:
201-762-9
MDL number:
Beilstein/REAXYS Number:
907431
Form:
solid
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Product Name

Pyrogallol, ACS reagent

grade

ACS reagent

Quality Level

vapor density

4.4 (vs air)

vapor pressure

10 mmHg ( 167.7 °C)

form

solid

ign. residue

≤0.005%

bp

309 °C ((lit.)), 309 °C (lit.)

mp

133-134 °C ((lit.)), 133-134 °C (lit.)

density

1.450 g/cm3 at 20 °C

anion traces

chloride (Cl-): ≤0.001%, sulfate (SO42-): ≤0.005%

cation traces

Fe: ≤0.001%, heavy metals (as Pb): ≤5 ppm

SMILES string

Oc1cccc(O)c1O

InChI

[1S/C6H6O3/c7-4-2-1-3-5(8)6(4)9/h1-3,7-9H], 1S/C6H6O3/c7-4-2-1-3-5(8)6(4)9/h1-3,7-9H

InChI key

[WQGWDDDVZFFDIG-UHFFFAOYSA-N], WQGWDDDVZFFDIG-UHFFFAOYSA-N

Application

Pyrogallol undergoes quick autooxidation in alkaline solution. Due to this property, its alkaline solution is generally used for the removal of oxygen from gases. Pyrogallol may also be used to prepare pyrogallol monomethyl ether via methylation and gallacetophenone via a modified Nencki reaction.
Metal-complexing agent


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pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Muta. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Protocols

该实验程序用于使用连苯三酚作为底物测定过氧化物酶的酶活性。

建立以 2,2'-连氮基-双(3-乙基苯并噻唑啉-6-磺酸)为基质的过氧化物酶测定方法。

To standardize a procedure for the assay of Peroxidase using 2,2'-Azino-bis(3-Ethylbenzthiazoline-6-Sulfonic Acid) as a substrate.

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Involvement of the superoxide anion radical in the autoxidation of pyrogallol and a convenient assay for superoxide dismutase.
Marklund S and Marklund G.
European Journal of Biochemistry, 47(3), 469-474 (1974)
Involvement of the superoxide anion radical in the autoxidation of pyrogallol and a convenient assay for superoxide dismutase
Marklund S & Marklund G
FEBS Journal, 47(3) (1974)
Gallacetophenone
Badhwar IC and Venkataraman K
Organic Syntheses, 14, 40-40 (1934)



Global Trade Item Number

SKUGTIN
254002-10G04061825982571
254002-50G04061825982618
254002-250G04061825982595