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32979

Acetamiprid-N-desmethyl

PESTANAL®, analytical standard

Synonym(s):

N-(6-Chloro-3-pyridylmethyl)-N′-cyano-acetamidine

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About This Item

Empirical Formula (Hill Notation):
C9H9ClN4
CAS Number:
190604-92-3
Molecular Weight:
208.65
NACRES:
NA.24
PubChem Substance ID:
329754419
UNSPSC Code:
41116107
MDL number:
MFCD08690484
Technical Service
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grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

C\C(NCc1ccc(Cl)nc1)=N/C#N

InChI

1S/C9H9ClN4/c1-7(14-6-11)12-4-8-2-3-9(10)13-5-8/h2-3,5H,4H2,1H3,(H,12,14)

InChI key

AYEAUPRZTZWBBF-UHFFFAOYSA-N

General description

Acetamiprid-N-desmethyl is a metabolite of the neonicotinoid insecticide, acetamiprid.

Application

Acetamiprid-N-desmethyl may be used as a reference standard in the determination of acetamiprid-N-desmethyl in urine samples using ultra high-performance liquid chromatography coupled with orbitrap high resolution mass spectrometry (UHPLC-HRMS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Acetamipride-Metabolite IM-2-1
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ0865
BCCD1153
BCBV6075
BCBV6076

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Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Neonicotinoids Ban: Impact on Plant Material

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

Relationship between urinary N-desmethyl-acetamiprid and typical symptoms including neurological findings: a prevalence case-control study
Marfo TJ, et al.
PLoS ONE, 10(11), e0142172-e0142172 (2015)
Richard C Kolanczyk et al.
Xenobiotica; the fate of foreign compounds in biological systems, 50(7), 805-814 (2019-11-15)
Providing an alternative to pyrethroids, organophosphates, and carbamates, the neonicotinoids are now the most widely used insecticides in the world. They are water soluble and relatively stable in soil and water which allows for run-off through surface waters and thus
Takamitsu Otake et al.
Journal of AOAC International, 103(6), 1469-1477 (2020-11-29)
Neonicotinoid insecticides (neonicotinoids) are widely used, however, they can negatively affect human health. Thus, neonicotinoids and their metabolites in human urine are analyzed globally to assess exposure levels and health risks. To properly assess the exposure levels and health risks
View All Related Papers

Global Trade Item Number

SKUGTIN
32979-10MG04061826720424