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Merck
CN

431400

Phosphomolybdic acid hydrate

≥99.99% trace metals basis

Synonym(s):

Molybdophosphoric acid

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About This Item

Linear Formula:
H3[P(Mo3O10)4] · xH2O
CAS Number:
Molecular Weight:
1825.25 (anhydrous basis)
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
234-713-5
MDL number:
Assay:
≥99.99% trace metals basis
Form:
crystals
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Quality Level

assay

≥99.99% trace metals basis

form

crystals

reaction suitability

reagent type: oxidant

impurities

≤0.01% insolubles, <100 ppm total metallic impurities

density

1.62 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.02%, sulfate (SO42-): ≤0.025%

cation traces

Ca: ≤0.02%, Fe: ≤0.005%, NH4+: ≤0.01%, heavy metals: ≤0.005%

SMILES string

O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O

InChI

1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;

InChI key

PDDXOPNEMCREGN-UHFFFAOYSA-N

General description

Phosphomolybdic acid hydrate is a heteropolyacid hydrate. It participates in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites. Phosphomolybdic acid is one of the components of the Goldner′s trichrome stain used for tissue staining.

Application

Employed in preparation of a hybrid organic-inorganic, electroactive material with potential application as a cation-insertion electrode in batteries.
Reactant for preparation of:
  • Catalysts for the nitration of aromatic compounds
  • Highly dispersed MoOx/CNTs (carbon nanotubes) as a support for Pt catalysts
  • Reduced molybdophosphate mixed-valence Keggin clusters
  • Polyoxometalate (POM) hybrid materials based on Keggin polyanion building blocks
  • Luminescent Langmuir-Blodgett films
  • Anchored Wilkinson catalyst
A precursor to hybrid organic-inorganic based molecular batteries with applications as cation-insertion electrodes.

Features and Benefits

Meets A.C.S. reagent specifications.


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Danger

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

pictograms

Corrosion

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials



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Liu, H.-Y.; et al.
Crystal Growth & Design, 11, 1786-1786 (2011)
Zhi Ming Cui et al.
Chemical communications (Cambridge, England), 47(29), 8418-8420 (2011-06-28)
HPMo self-assembly on carbon nanotubes followed by decomposition is used to fabricate highly dispersed MoO(x)/CNTs as a support for high performance of a Pt catalyst towards methanol oxidation.
Tomoyuki Akutagawa et al.
Inorganic chemistry, 50(14), 6711-6718 (2011-06-16)
Hydrogen-bonded assemblies of the two-electron reduced mixed-valence Keggin clusters [PMo(12)O(40)](5-) and [SiMo(12)O(40)](6-) were obtained by the one-pot electron-transfer reactions between p-phenylenediamine (PPD) or 2,3,5,6-tetramethyl-PPD (TMPPD) (donors) and H(+)(3)[PMo(12)O(40)](3-) or H(+)(4)[SiMo(12)O(40)](4-) (acceptors) in CH(3)CN. The redox states of the [PMo(12)O(40)](5-) and



Global Trade Item Number

SKUGTIN
431400-10G04061832108278
431400-50G04061838195890