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Merck
CN

936707

Me4tButylXPhos ChemBeads

greener alternative

solid

Synonym(s):

2-Di-tert-butylphosphino-3,4,5,6-tetramethyl-2′,4′,6′-triisopropyl-1,1′-biphenyl ChemBeads, Tetramethyl tBuXPhos ChemBeads, Tetramethyl di-tBuXPhos ChemBeads

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About This Item

Empirical Formula (Hill Notation):
C33H53P
CAS Number:
Molecular Weight:
480.75
UNSPSC Code:
12352100
MDL number:
NACRES:
NA.21
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Product Name

Me4tButylXPhos ChemBeads,

Quality Level

product line

ChemBeads

form

solid

composition

4-6 wt% loading

reaction suitability

reagent type: ligand

greener alternative product characteristics

Waste Prevention
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

CC1=C(C)C(C)=C(C)C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C1P(C(C)(C)C)C(C)(C)C

InChI

InChI=1S/C33H53P/c1-19(2)26-17-27(20(3)4)30(28(18-26)21(5)6)29-24(9)22(7)23(8)25(10)31(29)34(32(11,12)13)33(14,15)16/h17-21H,1-16H3

InChI key

RCRYEYMHBHPZQD-UHFFFAOYSA-N

General description

Me4tButylXPhos ChemBeads are the biaryl phosphine ligand Me4tButylXPhos coated on glass beads. For use in high-throughput expermentation (HTE).
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.

Application

Me4tButylXPhos can be used as a ligand in a range of C-C and C-N cross-coupling reactions such as Suzuki−Miyaura, Heck, and Buchwald-Hartwig amination reactions.

ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For general uses, product is also available in powdered form


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Global Trade Item Number

SKUGTIN
936707-1G04065272161046