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Merck
CN

I8507

Iodomethane

99%, liquid, suitable for synthesis, ReagentPlus®, contains copper as stabilizer

Synonym(s):

Methyl iodide

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About This Item

Empirical Formula (Hill Notation):
CH3I
CAS Number:
Molecular Weight:
141.94
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-819-5
MDL number:
Beilstein/REAXYS Number:
969135
Assay:
99%
Bp:
41-43 °C (lit.)
Vapor pressure:
24.09 psi ( 55 °C), 7.89 psi ( 20 °C)
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Product Name

Iodomethane, contains copper as stabilizer, ReagentPlus®, 99%

vapor density

4.89 (vs air)

Quality Level

vapor pressure

24.09 psi ( 55 °C), 7.89 psi ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

contains

copper as stabilizer

dilution

(for general lab use)

refractive index

n20/D 1.531 (lit.)

pH

6.3 (21.1 °C)

bp

41-43 °C (lit.)

mp

−64 (lit.)

density

2.28 g/mL at 25 °C (lit.)

functional group

alkyl halide, iodo

storage temp.

2-8°C

SMILES string

CI

InChI

1S/CH3I/c1-2/h1H3

InChI key

INQOMBQAUSQDDS-UHFFFAOYSA-N

General description

Iodomethane also known as methyl iodide is a methylating agent. Its potential as an alternative to methyl bromide for soil fumigation has been studied. The mechanism of the gas-phase reaction of iodomethane with chlorine atom has been described. The dynamics of photolysis of iodomethane have been studied using multiphoton ionization. The interaction of iodomethane with Cu(111) surface has been analyzed.

Application

Iodomethane (Methyl iodide) has been used to generate iodide water cluster reagent ions for ToF-CIMS (time-of-flight chemical ionization mass spectrometry) analysis. It may be used to prepare (E)-1-iodopropene and N,N,N-trimethylchitosan (TMC).

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

flash_point_f

89.8 °F - closed cup

flash_point_c

32.1 °C - closed cup

ppe

Faceshields, Gloves, Goggles

Regulatory Information

危险化学品

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Platinum-catalyzed addition of iodomethane to acetylene.
Mitchenko SA, et al.
Russian Chemical Bulletin, 62(4), 984-988 (2013)
Methylation of chitosan with iodomethane: effect of reaction conditions on chemoselectivity and degree of substitution.
Curti E, et al.
Macromolecular Bioscience, 3(10), 571-576 (2003)
Iodomethane dissociation on Cu (111): Bonding and chemistry of adsorbed methyl groups.
Lin JL and Bent BE.
Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, And Films, 10(4), 2202-2209 (1992)



Global Trade Item Number

SKUGTIN
I8507-100ML04061833858585
I8507-10KG04061833428443
I8507-500ML04061837550751
I8507-5G04061837550768
I8507-5ML04061837550775
I8507-100G04061833858578
I8507-1L04061833858592
I8507-25KG04061833858608
I8507-2KG04061837550720
I8507-4X100G04061833858615
I8507-500G04061833858622