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Merck
CN

M4141

Methanesulfonic acid solution

4 M (with 0.2% (w/v) tryptamine)

Synonym(s):

Sulfomethane

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About This Item

Linear Formula:
CH3SO3H
CAS Number:
Molecular Weight:
96.11
UNSPSC Code:
12352209
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-898-6
Beilstein/REAXYS Number:
1446024
MDL number:
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form

liquid

Quality Level

concentration

4 M (with 0.2% (w/v) tryptamine)

storage temp.

2-8°C

SMILES string

CS(O)(=O)=O

InChI

1S/CH4O3S/c1-5(2,3)4/h1H3,(H,2,3,4)

InChI key

AFVFQIVMOAPDHO-UHFFFAOYSA-N

Application

For complete protein and peptide hydrolysis with tryptophan recovery. After hydrolysis the samples are diluted prior to amino acid analysis.

Packaging

Ampules sealed under argon.

Disclaimer

air sensitive, store under inert conditions


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 2

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Luke F Gamon et al.
Redox biology, 36, 101586-101586 (2020-06-07)
The precise characterization and quantification of oxidative protein damage is a significant challenge due to the low abundance, large variety, and heterogeneity of modifications. Mass spectrometry (MS)-based techniques at the peptide level (proteomics) provide a detailed but limited picture due
Norio Murai et al.
Organic letters, 14(11), 2818-2821 (2012-05-18)
A one-pot primary aminomethylation of aryl halides, triflates, mesylates, and tosylates via Suzuki-Miyaura cross-coupling reactions with sodium phthalimidomethyltrifluoroborate followed by deamidation with ethylenediamine is reported.
Solvejg Jørgensen et al.
Physical chemistry chemical physics : PCCP, 15(14), 5140-5150 (2013-03-02)
The gas phase reaction between methane sulfonic acid (CH3SO3H; MSA) and the hydroxyl radical (HO), without and with a water molecule, was investigated with DFT-B3LYP and CCSD(T)-F12 methods. For the bare reaction we have found two reaction mechanisms, involving proton



Global Trade Item Number

SKUGTIN
M4141-10X2ML04061837841088