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Merck
CN

209139

Silver nitrate

ACS reagent, ≥99.0%

Synonym(s):

Nitric acid silver(I) salt

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About This Item

Linear Formula:
AgNO3
CAS Number:
Molecular Weight:
169.87
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-853-9
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
solid
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grade

ACS reagent

Quality Level

vapor density

5.8 (vs air)

assay

≥99.0%

form

solid

reaction suitability

reagent type: catalyst
core: silver

clarity of soln

passes test

impurities

Free acid, passes test, ≤0.01% not HCl pptd.

mp

212 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤5 ppm, sulfate (SO42-): ≤0.002%

cation traces

Cu: ≤2 ppm, Fe: ≤2 ppm, Pb: ≤0.001%

SMILES string

[O-][N+]([O-])=O.[Ag+]

InChI

1S/Ag.NO3/c;2-1(3)4/q+1;-1

InChI key

SQGYOTSLMSWVJD-UHFFFAOYSA-N

General description

Silver nitrate, also known as Nitric acid silver(I) salt, is an odorless, colorless, or white versatile inorganic compound widely used as an oxidant and cauterizing agent due to its sclerosing, dehydrating, and escharotic properties. It is commonly used as a catalyst in the hydrolytic oxidation of organosilanes, leading to the production of high hydrogen yield and organosilanols.

Application

Silver nitrate can be used as a catalyst:      
  • For the Friedel-Crafts acylation of benzene derivatives to synthesize corresponding ketones.     
  • In the hydrolytic oxidation of organosilanes to produce hydrogen.

It can be used to prepare some supported acid catalysts for various organic transformations. For example:      
  • AgNO3–SiO2 based catalyst is used to dearomatize spirocyclization.      
  • Polyaniline-AgNO3-PTSA (para-toluene sulfonic acid) catalyst is used to synthesize anti-β-amino ketones via the three-component Mannich reaction of aromatic aldehydes, aromatic amines, and cyclohexanone.

AgNO3 is also used as a precursor salt to synthesize silver nanoparticles.


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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Repr. 1B - Skin Corr. 1A

Storage Class

5.1B - Oxidizing hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
易制爆化学品

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Catalytic hydrogen evolution from hydrolytic oxidation of organosilanes with silver nitrate catalyst
Teo AKL and Fan WY
Royal Society of Chemistry Advances, 4(71), 37645-37648 (2014)
Hongyan Yang et al.
Antibiotics (Basel, Switzerland), 9(11) (2020-11-01)
Antimicrobial resistance is currently an important concern, but there are few data on the co-presence of metal and antibiotic resistance in potentially pathogenic Escherichia coli entering the food chain from pork, which may threaten human health. We have examined the
D D Songstad et al.
Plant cell reports, 7(4), 262-265 (1988-06-01)
The effect of the ethylene antagonists norbornadiene and silver nitrate and the ethylene precursor l-aminocyclopropane-l-carboxylic acid (ACC) on Zea mays plant regeneration was studied. A 12-fold increase in plant regeneration, as measured by number of plants obtained per gram fresh



Global Trade Item Number

SKUGTIN
209139-100G04061837768408
209139-25G04061837768422
209139-500G04061837768439