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Merck
CN

221864

Potassium bromide

greener alternative

≥99% trace metals basis

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About This Item

Linear Formula:
KBr
CAS Number:
Molecular Weight:
119.00
PubChem Substance ID:
eCl@ss:
38050405
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-830-3
MDL number:
Assay:
≥99% trace metals basis
Form:
powder or crystals
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Quality Level

vapor pressure

<0.01 mmHg ( 20 °C), 1 mmHg ( 795 °C)

assay

≥99% trace metals basis

form

powder or crystals

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

technique(s)

FTIR: suitable

pH

5-6 (25 °C, 119 g/L)

mp

734 °C (lit.)

greener alternative category

SMILES string

[K+].[Br-]

InChI

1S/BrH.K/h1H;/q;+1/p-1

InChI key

IOLCXVTUBQKXJR-UHFFFAOYSA-M

General description

Potassium bromide, a water-soluble inorganic salt, is redox reagent.

Application

Potassium bromide may be used along with:
  • Cerium(IV) ammonium nitrate (CAN) for synthesizing dibromides via alkene bromination.
  • Sodium perborate for synthesizing brominated anilines via oxidative bromination of unprotected aromatic amines.
  • Hydrochloric acid and hydrogen peroxide for the bromination of active methylene and methyne compounds with high chemoselectivity.
May be used for removal of peripheral membrane proteins.
Suitable for use with FT-IR spectrometers

Features and Benefits

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.


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Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

13 - Non Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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Chemoselective bromination of active methylene and methyne compounds by potassium bromide, hydrochloric acid and hydrogen peroxide.
Shimosaki R, et al.
Synlett, 2006(14), 2287-2289 (2006)
Mild and regioselective oxidative bromination of anilines using potassium bromide and sodium perborate.
Roche D, et al.
Tetrahedron Letters, 41(13), 2083-2085 (2000)
Ville Petteri Heljo et al.
Pharmaceutical research, 28(3), 540-552 (2010-10-23)
The purpose of this study is to show how disaccharides differ in their ability to protect lyophilized β-galactosidase from enzymatic activity loss and secondary structure changes during storage. β-galactosidase was lyophilized with trehalose, sucrose, cellobiose or melibiose at 2:1, 20:1



Global Trade Item Number

SKUGTIN
221864-100G04061835276646
221864-25G04061835276653