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Merck
CN

223425

Potassium oxalate monohydrate

ACS reagent, 99%

Synonym(s):

Ethanedioic acid, Oxalic acid potassium salt

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About This Item

Linear Formula:
(COOK)2 · H2O
CAS Number:
Molecular Weight:
184.23
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-506-8
Beilstein/REAXYS Number:
3752576
MDL number:
Assay:
98.5-101.0% (ACS specification), 99%
Grade:
ACS reagent
Form:
crystals or chunks
Solubility:
H2O: 10%
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grade

ACS reagent

Quality Level

description

neutrality passes test

assay

98.5-101.0% (ACS specification), 99%

form

crystals or chunks

impurities

H2SO4, passes test (darkened), ≤0.01% insolubles

pH

7.0-8.5 (25 °C, 50 g/L)

solubility

H2O: 10%

anion traces

chloride (Cl-): ≤0.002%, sulfate (SO42-): ≤0.01%

cation traces

Fe: ≤0.001%, NH4+: ≤0.002%, Na: ≤0.02%, heavy metals: ≤0.002% (by ICP)

SMILES string

O.[K+].[K+].[O-]C(=O)C([O-])=O

InChI

1S/C2H2O4.2K.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);;;1H2/q;2*+1;/p-2

InChI key

QCPTVXCMROGZOL-UHFFFAOYSA-L

General description

Potassium oxalate monohydrate (POM) is a potassium salt of oxalic acid. Its crystal structure has been investigated by three-dimensional neutron diffraction studies.

Application

Potassium oxalate monohydrate may be used in the preparation of SBA-15 (Santa Barbara Amoprhous-15)- catalyst.
Potassium oxalate monohydrate may be used in the synthesis of bis(2,2"-bipyridine) (oxalato-O,O′)nickel(ii) tetrahydrate, a mononuclear mixed-ligand complex.


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Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 1



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Solid-state chemistry of nickel (II)-oxalate-amine systems. Synthesis, characterization and crystal structure of the bis (2, 2'-bipyridine)(oxalato-O, O') nickel (II) tetrahydrate.
Roman P, et al.
Polyhedron, 14(20), 2863-2869 null
EPR and optical absorption studies of vanadyl ions in potassium oxalate monohydrate.
Kripal R, et al.
Physica B: Condensed Matter (Amsterdam, Netherlands), 392(1), 281-287 (2007)
Neutron diffraction refinement of the structure of potassium oxalate monohydrate.
Sequeira A, et al.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 26(1), 77-80 (1970)



Global Trade Item Number

SKUGTIN
223425-2.5KG04061832562827
223425-12KG04061833636572
223425-500G04061838778437