366374
Zinc chloride solution
0.5 M in THF
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About This Item
Linear Formula:
ZnCl2
CAS Number:
Molecular Weight:
136.30
UNSPSC Code:
12352302
NACRES:
NA.55
PubChem Substance ID:
MDL number:
Form:
liquid
form
liquid
Quality Level
concentration
0.5 M in THF, 470-600 mmol/L (silver nitrate titration)
density
0.948 g/mL at 25 °C
SMILES string
Cl[Zn]Cl
InChI
1S/2ClH.Zn/h2*1H;/q;;+2/p-2
InChI key
JIAARYAFYJHUJI-UHFFFAOYSA-L
General description
Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.
Application
Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
Regulatory Information
危险化学品
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Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
Wang MCP, et al.
Electrochimica Acta, 53(26), 7720-7725 (2008)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 366374-100ML | 04061831826074 |
| 366374-800ML | 04061837633577 |