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Merck
CN

746479

Lithium bromide

anhydrous, free-flowing, Redi-Dri, ReagentPlus®, ≥99%

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About This Item

Linear Formula:
LiBr
CAS Number:
Molecular Weight:
86.85
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-439-8
MDL number:
Assay:
≥99%
Grade:
anhydrous
Form:
powder
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grade

anhydrous

Quality Level

vapor pressure

1 hPa ( 748 °C)

product line

ReagentPlus®, Redi-Dri

assay

≥99%

form

powder

quality

free-flowing

pH

7 (20 °C, 10 g/L)

mp

550 °C (lit.)

SMILES string

[Li+].[Br-]

InChI

1S/BrH.Li/h1H;/q;+1/p-1

InChI key

AMXOYNBUYSYVKV-UHFFFAOYSA-M

General description

Lithium bromide is a versatile reagent that is commonly used as a nucleophilic brominating reagent. It is also employed as a Lewis acid catalyst and a mediator in various reactions.

Application

Lithium bromide can be used as a catalyst in the:
  • Solvent-free condensation of arylene diamines and esters to synthesize 2-substituted benzimidazoles and imidazopyridines.
  • Three-component condensation of aldehydes, β-ketoesters, and urea to synthesize dihydropyrimidinones via Biginelli reaction.
  • Solvent-free Ehrlich-Sachs reaction.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC


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pictograms

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

No data available

flash_point_c

No data available



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Articles

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.


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Global Trade Item Number

SKUGTIN
746479-1KG04061832891330
746479-2.5KG04061832581095
746479-100G04061832891323
746479-500G04061832891347
746479-6X500G04061832581101