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About This Item
Linear Formula:
K2CO3
CAS Number:
Molecular Weight:
138.21
UNSPSC Code:
12352302
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-529-3
Beilstein/REAXYS Number:
4267587
MDL number:
Assay:
≥98%
Grade:
anhydrous, reagent grade
Form:
powder
Quality Level
grade
anhydrous, reagent grade
product line
Redi-Dri™
assay
≥98%
form
powder
quality
free-flowing
particle size
−325 mesh
pH
11-13 (25 °C, 138 g/L)
mp
891 °C (lit.)
SMILES string
[K+].[K+].[O-]C([O-])=O
InChI
1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
BWHMMNNQKKPAPP-UHFFFAOYSA-L
General description
Potassium carbonate is an inorganic base. It participates as base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene.
Application
Potassium carbonate was used in the following studies:
- Synthesis of polysubstituted iodobenzene derivatives.
- As base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
- As base for the Suzuki coupling of aryl halides with aryl boronic acids.
- As base for the Heck reaction of styrene and bromobenzene.
Legal Information
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Heck reaction catalyzed by phospha-palladacycles in non-aqueous ionic liquids.
Herrmann WA and Bohm VPW.
Journal of Organometallic Chemistry, 572(1), 141-145 (1999)
Heck reaction using palladium complexed to dendrimers on silica.
Alper H, et al.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 900502-12KG | 04061832581446 |
| 900502-1KG | 04061824806748 |
| 900502-2.5KG | 04061832581453 |
| 900502-500G | 04061832581460 |
