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Merck
CN

P5958

Potassium hydroxide

BioXtra, ≥85% KOH basis

Synonym(s):

Caustic potash

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About This Item

Linear Formula:
KOH
CAS Number:
Molecular Weight:
56.11
PubChem Substance ID:
eCl@ss:
38100303
UNSPSC Code:
12352106
NACRES:
NA.21
EC Number:
215-181-3
MDL number:
Assay:
≥85% KOH basis
Form:
pellets
Solubility:
H2O: 1 M, clear, colorless
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vapor pressure

1 mmHg ( 719 °C)

product line

BioXtra

assay

≥85% KOH basis

form

pellets

impurities

≤0.0005% Phosphorus (P), ≤0.1% Insoluble matter, ≤2.0% K2CO3

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

solubility

H2O: 1 M, clear, colorless

anion traces

chloride (Cl-): ≤0.01%, sulfate (SO42-): ≤0.003%

cation traces

Al: ≤0.0005%, Ca: ≤0.0005%, Cu: ≤0.0005%, Fe: ≤0.0005%, Mg: ≤0.0005%, NH4+: ≤0.05%, Na: ≤0.05%, Pb: ≤0.001%, Zn: ≤0.0005%

SMILES string

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

General description

Potassium hydroxide is an inorganic compound commonly known as caustic potash. It is a strong alkali, readily reacts with acids. It can be used in various reactions such as nucleophilic substitution, hydrolysis, and addition reactions. Sometimes it can also be used as a catalyst for aldol-type reactions.

Application

Potassium hydroxide can be used to adjust the pH of the solution.
It can also be used:
  • As a catalyst in the alkynylation of heteroaromatic N-oxides to synthesize corresponding C2-alkynylheterocycles.
  • As a superbase medium with dimethyl sulfoxide (KOH/DMSO medium) for the synthesis of cross-coupling products under transition metal-free conditions from reactions between aryl halides and various sulfur, oxygen and nitrogen-based nucleophiles.
  • In the synthesis and thermodynamic study of Na-based zeolites.



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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Global Trade Item Number

SKUGTIN
P5958-1KG04061834392682
P5958-250G04061834392699
P5958-500G04061835567812