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Merck
CN

51269

Dihydroxyacetone phosphate hemimagnesium salt hydrate

≥95% (TLC)

Synonym(s):

1,3-Dihydroxy-2-propanone 1-phosphate hemimagnesium salt hydrate, 1-Hydroxy-3-(phosphonooxy)-2-propanone hemimagnesium salt hydrate, DHAP Mg

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About This Item

Empirical Formula (Hill Notation):
C3H5Mg0.5O6P · xH2O
CAS Number:
Molecular Weight:
180.19 (anhydrous basis)
MDL number:
UNSPSC Code:
12352107
PubChem Substance ID:
NACRES:
NA.25
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Quality Level

assay

≥95% (TLC)

storage temp.

−20°C

SMILES string

O.OCC(=O)COP(O)(=O)O[Mg]OP(O)(=O)OCC(=O)CO

InChI

1S/2C3H7O6P.Mg.H2O/c2*4-1-3(5)2-9-10(6,7)8;;/h2*4H,1-2H2,(H2,6,7,8);;1H2/q;;+2;/p-2

InChI key

XIBMKSGIYJARCI-UHFFFAOYSA-L

Application

Dihydroxyacetone phosphate hemimagnesium salt hydrate (DHAP Mg) is a magnesium salt of DHAP. DHAP may be used as the substrate to characterize enzymes such as fructose bisphosphate aldolase and triose phosphate isomerase.

Biochem/physiol Actions

Dihydroxyacetone phosphate (DHAP) is a metabolic intermediate involved in many pathways, including glycolysis, gluconeogenesis, glycerol metabolism, phosphatidic acid synthesis, fat metabolism, and the Calvin cycle.


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Matthias Bujara et al.
Nature chemical biology, 7(5), 271-277 (2011-03-23)
Recruiting complex metabolic reaction networks for chemical synthesis has attracted considerable attention but frequently requires optimization of network composition and dynamics to reach sufficient productivity. As a design framework to predict optimal levels for all enzymes in the network is
Ferenc Orosz et al.
Biochimica et biophysica acta, 1792(12), 1168-1174 (2009-09-30)
The triosephosphate isomerase (TPI) functions at a metabolic cross-road ensuring the rapid equilibration of the triosephosphates produced by aldolase in glycolysis, which is interconnected to lipid metabolism, to glycerol-3-phosphate shuttle and to the pentose phosphate pathway. The enzyme is a
Bjørn O Hald et al.
The FEBS journal, 279(23), 4410-4420 (2012-10-18)
Coherent glycolytic oscillations in Saccharomyces cerevisiae are a multicellular property induced by addition of glucose to a starved cell population of sufficient density. However, initiation of oscillations requires an additional perturbation, usually addition of cyanide. The fate of cyanide during



Global Trade Item Number

SKUGTIN
51269-100MG04061832492339
51269-500MG04061832404530