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Merck
CN

90335

Triethylamine

BioUltra, ≥99.5% (GC)

Synonym(s):

N,N-Diethylethanamine

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About This Item

Linear Formula:
(C2H5)3N
CAS Number:
Molecular Weight:
101.19
UNSPSC Code:
12352116
NACRES:
NA.25
PubChem Substance ID:
EC Number:
204-469-4
Beilstein/REAXYS Number:
605283
MDL number:
Assay:
≥99.5% (GC)
Technique(s):
ion chromatography: suitable
Bp:
88.8 °C (lit.)
Vapor pressure:
51.75 mmHg ( 20 °C)
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vapor density

3.5 (vs air)

Quality Level

vapor pressure

51.75 mmHg ( 20 °C)

product line

BioUltra

assay

≥99.5% (GC)

form

liquid

autoignition temp.

593 °F

shelf life

36 mo.

expl. lim.

8 %

technique(s)

ion chromatography: suitable

impurities

insoluble matter, passes filter test, ≤0.5% water

evapn. residue

≤0.003%

refractive index

n20/D 1.401 (lit.)

pH

12.7 (15 °C, 100 g/L)

bp

88.8 °C (lit.)

mp

−115 °C (lit.)

density

0.726 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.2 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.02 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg

absorption

cut-off at 278 nm

storage temp.

2-8°C

SMILES string

CCN(CC)CC

InChI

1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

ZMANZCXQSJIPKH-UHFFFAOYSA-N

General description

Triethyl amine (TEA) is an aliphatic tertiary amine.

Application

Triethylamine has been used to bind the n-hydroxysuccinimide (NHS) group with the amino-treated tip surface. It has also been used as a basic catalyst for acylation.

Biochem/physiol Actions

Triethylamine (TEA) may play a dual role as a base and a solubilizing agent for promoting the reaction in toluene and TEA.
Triethylamine, a mobile-phase modifier, is used in the reversed-phase high-performance liquid chromatography (RP-HPLC) separation of acidic, basic, and neutral molecules. It improves the resolution of amino acids and amino acids amides by suppressing the tailing and the stability of drugs and other compounds.

Other Notes

Component of volatile buffer system in ion-exchange HPLC of oligonucleotides


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signalword

Danger

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

flash_point_f

12.2 °F - closed cup

flash_point_c

-11 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Regulatory Information

危险化学品

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Protocols

Sildenafil, sold under the brand name Viagra, among others, is a medication used to treat erectile dysfunction and pulmonary arterial hypertension.


J M Munholland et al.
Analytical biochemistry, 178(2), 320-323 (1989-05-01)
A volatile buffer has been adapted for use with ion-exchange high-performance liquid chromatography in the analysis and preparation of oligonucleotides. The system employs a commercial weakly basic anion-exchange column containing a DEAE-derivatized silica gel and eluted with a volatile buffer
Javier Sotres et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 9(4), 590-599 (2008-02-26)
Atomic force microscopy is a technique capable to study biological recognition processes at the single-molecule level. In this work we operate the AFM in a force-scan based mode, the jumping mode, where simultaneous topographic and tip-sample adhesion maps are acquired.
Sumanta Kumar Padhi et al.
Inorganic chemistry, 51(15), 8091-8102 (2012-07-26)
Cyclometalated ruthenium complexes having C(^)N and N(^)C type coordinating ligands with NAD(+)/NADH function have been synthesized and characterized by spectroscopic methods. The variation of the coordinating position of σ-donating carbon atom leads to a drastic change in their properties. Both



Global Trade Item Number

SKUGTIN
M1381-25G04061834038207
Y000001104061833801666
M1381-100G04061835559503
90335-1L04061838254498
90335-100ML04061833246672
90335-250ML04061833246689