215813
氢化钾
30 wt % dispersion in mineral oil
别名:
Potassium monohydride
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关于此项目
线性分子式:
KH
化学文摘社编号:
分子量:
40.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-704-8
MDL number:
Form:
slurry
form
slurry
Quality Level
reaction suitability
reagent type: reductant
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
30 wt % dispersion in mineral oil
greener alternative category
, Enabling
SMILES string
[K]
InChI
1S/K.H
InChI key
NTTOTNSKUYCDAV-UHFFFAOYSA-N
General description
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了能源效率。点击此处，查看更多详情。
Application
Potassium hydride can be used for following applications:
- Deprotonation: As a strong base, potassium hydride effectively deprotonates hydroxyl groups of monomers, generating alkoxide ions. These ions facilitate the ring-opening polymerization of monosubstituted oxiranes.
- Strong Base in Williamson Ether Synthesis: It is employed to generate alkoxides from alcohols, which subsequently react with alkyl halides to form ethers.
- Reducing Agent: Potassium hydride can reduce hindered boranes and borates to trialkyl borohydrides. It also facilitates the reduction of ketones and alkyl halides.
- Alkylation and Enolate Formation: It aids in the formation of enolates from ketones, which can be utilized in one-pot alkylation-cyclization reactions.
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Danger
hcodes
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - Water-react. 1
Patnaik P et al.
A Comprehensive Guide to the Hazardous Properties of Chemical Substances null
Potassium hydride in paraffin: A useful base for organic synthesis.
Taber DF and Nelson CG
The Journal of Organic Chemistry, 71(23), 8973-8974 (2006)
David K Packham et al.
The New England journal of medicine, 372(3), 222-231 (2014-11-22)
Hyperkalemia (serum potassium level, >5.0 mmol per liter) is associated with increased mortality among patients with heart failure, chronic kidney disease, or diabetes. We investigated whether sodium zirconium cyclosilicate (ZS-9), a novel selective cation exchanger, could lower serum potassium levels
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 215813-300G | 04061838773975 |
| 215813-75G | 04061838773982 |