Quality Level
assay
97%
reaction suitability
reagent type: oxidant
mp
180-184 °C (lit.)
functional group
ether
storage temp.
2-8°C
SMILES string
C[N+]1([O-])CCOCC1
InChI
1S/C5H11NO2/c1-6(7)2-4-8-5-3-6/h2-5H2,1H3
InChI key
LFTLOKWAGJYHHR-UHFFFAOYSA-N
General description
N-甲基吗啉N氧化物是一种有机化合物,在有机合成中与 OsO4和钌酸盐一起用作共氧化剂。在最近的研究中,其已用作醛酮硅氰化反应的催化剂。绿色纤维(Lyocell)是一种再生纤维素纤维,可由N-甲基吗啉N氧化物通过环保方式制得。
Application
用于酮的硅氰化反应的非金属催化剂。用于离子液体中 Sharpless 不对称双羟基化反应的助氧化剂。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Repr. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
N?Methylmorpholine N?Oxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2008)
Nicolas Dupuy et al.
The Journal of chemical physics, 142(21), 214109-214109 (2015-06-08)
We study the ionization energy, electron affinity, and the π → π(∗) ((1)La) excitation energy of the anthracene molecule, by means of variational quantum Monte Carlo (QMC) methods based on a Jastrow correlated antisymmetrized geminal power (JAGP) wave function, developed
Luís C Branco et al.
The Journal of organic chemistry, 69(13), 4381-4389 (2004-06-19)
The use of room-temperature ionic liquids (RTILs) in the Sharpless catalytic asymmetric dihydroxylation (AD) as a cosolvent or replacement of the tert-butanol was studied in detail by screening 11 different RTILs. The AD reaction is faster in 1-n-butyl-3-methylimidazolium hexafluorophosphate [C(4)mim][PF(6)]
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 224286-100G | 04061838778888 |
| 224286-25G | 04061838778895 |
| 224286-5G | 04061838778901 |

