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230197

三乙基硅烷

99%

别名:

NSC 93579, 三乙基硅烷

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关于此项目

线性分子式:
(C2H5)3SiH
化学文摘社编号:
617-86-7
分子量:
116.28
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24853781
EC Number:
210-535-3
Beilstein/REAXYS Number:
1098278
MDL number:
MFCD00009018
Assay:
99%
Form:
liquid
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Quality Level

200

assay

99%

form

liquid

reaction suitability

reagent type: reductant

refractive index

n20/D 1.412 (lit.)

bp

107-108 °C (lit.)

density

0.728 g/mL at 25 °C (lit.)

SMILES string

CC[SiH](CC)CC

InChI

1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

InChI key

AQRLNPVMDITEJU-UHFFFAOYSA-N

Application

作为以下研究的催化剂：
  • 用于合成治疗疼痛的螺羟吲哚类 NaV1.7阻断剂
  • 氧化还原引发的阳离子聚合
  • 环十二酮肟的Beckmann重排
  • 烯酮和丙二烯的区域选择性还原偶联

苯乙烯催化剂聚合后的催化剂再活化

有机硅闪点预测的相关研究
多功能还原剂
用于 2-色原烷醇还原反应的研究；与 TES 可观察到顺式选择性。

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

21.2 °F

flash_point_c

-6 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBK4815
STBJ8363
STBJ4855
STBH8482
STBH4393

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Kelin Li et al.
Organic letters, 8(21), 4711-4714 (2006-10-06)
[reaction: see text] Reduction of C5-substituted 2-hydroxychromans selectively provides 2,4-cis-chromans using large silane reductants and 2,4-trans-chromans using the smaller silane PhSiH(3). The stereochemical outcome has been rationalized on the basis of a Curtin-Hammett kinetic situation arising from hydride delivery to
Zaihui Zhang et al.
Journal of medicinal chemistry, 56(2), 568-583 (2012-12-19)
Stearoyl-CoA desaturase-1 (SCD1) catalyzes de novo synthesis of monounsaturated fatty acids from saturated fatty acids. Studies have demonstrated that rodents lacking a functional SCD1 gene have an improved metabolic profile, including reduced weight gain, lower triglycerides, and improved insulin response.
Sultan Chowdhury et al.
Bioorganic & medicinal chemistry letters, 21(12), 3676-3681 (2011-05-17)
Starting from the oxindole 2a identified through a high-throughput screening campaign, a series of Na(V)1.7 blockers were developed. Following the elimination of undesirable structural features, preliminary optimization of the oxindole C-3 and N-1 substituents afforded the simplified analogue 9b, which
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全球贸易项目编号

货号GTIN
230197-25G04061838782434
230197-100G04061838782427
230197-500G04061833498781
230197-5G04061838782441