assay
≤77%
form
solid
reaction suitability
reagent type: oxidant
mp
69-71 °C (lit.)
functional group
chloro, hydroperoxide
storage temp.
2-8°C
SMILES string
OOC(=O)c1cccc(Cl)c1
InChI
1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H
InChI key
NHQDETIJWKXCTC-UHFFFAOYSA-N
General description
3-氯过苯甲酸是一种强氧化剂，主要用于烯烃的环氧化反应以及从酮到酯的Baeyer-Villiger氧化。
Application
3-氯过苯甲酸已用于从N-邻-甲苯基亚砜基-(E)-1-苯乙基亚胺至N-邻-甲苯磺酰(E)-1-苯乙基亚胺的氧化，其中使用二氯甲烷作为溶剂。它还用于制备单-和二-环氧-官能化的聚（3-羟基丁酸酯）基反应性聚合物。MCPBA还是一种有效的氧化剂，用于将α-酰胺取代的聚酯转化为具有可调节热属性的相应聚砜。
用于环氧化二-，三-和四-取代烯烃的有效氧化剂。
Other Notes
残留物为 3-氯苯甲酸和水
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
商品
Baeyer-Villiger氧化是与羰基相邻的碳-碳键的氧化裂解，其可将酮转化为酯、环酮转化为内酯。
The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.
Chiral Mn (III) salen complexes covalently bonded on modified MCM-41 and SBA-15 as efficient catalysts for enantioselective epoxidation of nonfunctionalized alkenes.
Kureshy R
J. Catal., 238(1), 134-141 (2006)
Rearrangements of organic peroxides and related processes.
Yaremenko I
Beilstein Journal of Organic Chemistry, 12, 1647-1647 (2016)
Preparation of N?p?Tolylsulfonyl?(E)?1?Phenylethylideneimine.
Ruano J
Organic Syntheses, 129-138 (2007)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 273031-25G | 04061835521302 |
| 273031-500G | 04061835554850 |
| 273031-100G | 04061835554843 |
| 273031-10KG | 04061835511914 |
| 273031-1KG | 04061835489565 |