302120
正丁基锂 溶液
2.0 M in cyclohexane
别名:
1-丁基锂, n-BuLi, Butyl lithium, 丁基锂 溶液
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关于此项目
线性分子式:
CH3(CH2)3Li
化学文摘社编号:
分子量:
64.06
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1209227
Concentration:
2.0 M in cyclohexane
Form:
liquid
form
liquid
Quality Level
concentration
2.0 M in cyclohexane
bp
80 °C
density
0.775 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI key
MZRVEZGGRBJDDB-UHFFFAOYSA-N
General description
正丁基锂(n-BuLi)是有机锂试剂，在无机合成中广泛用作强碱（超强碱），用于各种化学中间体的制备。也作为试剂，用于锂卤交换反应和锂-金属的金属交换反应。正丁基锂可锂化碳酸类化合物(carbon acids)。
Application
正丁基锂（2.0 M环己烷溶液）可用作：
- 聚合引发剂，通过阴离子聚合苯乙烯合成聚苯乙烯。
- 强碱，用于非对映选择性烷基化反应。
- 作为试剂与苯甲醛类和二(1H-吡咯-1-yl)四氯化锆反应合成2-苯甲酰基吡咯。
Packaging
建议将25 mL Sure/Seal™瓶作为一次性瓶使用。 反复扎刺可能会使产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
危险化学品
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商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
Comparison of the synthetic utility of n-butyllithium and lithium diisopropylamide in the metalations of N, N-dialkyltoluamides.
Ludt RE, et al
The Journal of Organic Chemistry, 38(9), 1668-1674 (1973)
Arene-metal complexes. 13. Reaction of substituted (benzene) tricarbonylchromium complexes with n-butyllithium.
Card RJ and Trahanovsky WS.
The Journal of Organic Chemistry, 45(13), 2560-2566 (1980)
Lithium intercalation via n-butyllithium of the layered transition metal dichalcogenides.
Dines MB.
Materials Research Bulletin, 10(4), 287-291 (1975)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 302120-PZ | 04061823822282 |
| 302120-100ML | 04061837881015 |
| 302120-4X25ML | 04061826665725 |
| 302120-800ML | 04061837881022 |