416665
叔丁基过氧化氢 溶液
5.0-6.0 M in decane
别名:
2-过氧化氢-2-甲基丙烷, 1,1-二甲基乙基-过氧化氢, TBHP
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关于此项目
线性分子式:
(CH3)3COOH
化学文摘社编号:
分子量:
90.12
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1098280
form
liquid
Quality Level
reaction suitability
reagent type: oxidant
concentration
5.0-6.0 M in decane, 55.4-65.1% (Thiosulphate, titration)
impurities
<4% water
refractive index
n20/D 1.402
density
0.808 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
General description
叔丁基氢过氧化物是一种有机过氧化物，可用于氧化过程。
Application
叔丁基氢过氧化物可用于：
锇催化烯烃在碱性条件下的邻位羟基化
使用联萘酚作为手性助剂，将硫化物催化不对称氧化成亚砜
二苯并噻吩的氧化
锇催化烯烃在碱性条件下的邻位羟基化
使用联萘酚作为手性助剂，将硫化物催化不对称氧化成亚砜
二苯并噻吩的氧化
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Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Catalytic asymmetric oxidation of sulfides to sulfoxides with tert-butyl hydroperoxide using binaphthol as a chiral auxiliary
Komatsu N, et al.
The Journal of Organic Chemistry, 58(17), 4529-4533 (1993)
Osmium catalyzed vicinal hydroxylation of olefins by tert-butyl hydroperoxide under alkaline conditions.
Sharpless KB and Akashi K
Journal of the American Chemical Society, 98(7), 1986-1987 (1976)
Oxidative desulfurization of fuel oil: Part I. Oxidation of dibenzothiophenes using tert-butyl hydroperoxide.
Wang D, et al.
Applied Catalysis A: General, 91-99 (2003)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 416665-25ML | 04061832089782 |
| 416665-100ML | 04061832089775 |
| 416665-1L | 04065274119076 |