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904694

Ir(p-CF3-ppy)3

≥95%, powder or crystals

别名:

三[2-(2-吡啶-κN)-5-(三氟甲基)苯基-κC]铱

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关于此项目

经验公式（希尔记法）:
C36H21F9IrN3
化学文摘社编号:
500295-52-3
分子量:
858.77
MDL number:
MFCD31657272
UNSPSC Code:
12161600
NACRES:
NA.22
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产品名称

Ir(p-CF3-ppy)3, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

[Ir]741([NH]8=C(c9c7cc(cc9)C(F)(F)F)C=CC=C8)([NH]5=C(c6c4cc(cc6)C(F)(F)F)C=CC=C5)[NH]2=C(c3c1cc(cc3)C(F)(F)F)C=CC=C2

InChI

1S/3C12H7F3N.Ir/c3*13-12(14,15)10-6-4-9(5-7-10)11-3-1-2-8-16-11;/h3*1-4,6-8H;

InChI key

ZLVNAIXHGHEODI-UHFFFAOYSA-N

Application

这种光催化剂促进使用可见光的多种转化，包括芳烃的脱氟。

产品可与我们的光反应器系列配合使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

Other Notes

用于光催化的均配和杂配环金属化铱（III）配合物的简便合成和完整表征

光催化 CF 烷基化；容易获得多氟化芳烃

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A Singh et al.
Chemical science, 6(12), 7206-7212 (2015-12-01)
C-F functionalizations that provide C-C bonds are challenging synthetic transformations, due in part to the large C-F bond strength, short bond length, nonpolarizable nature, the production of fluoride, and the regioselectivity-in the case of multifluorinated substrates. However, commercially available highly
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)