主要文件

查看所有文档

902225

Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆

Name: Ir[dFMeppy]2-(4,4&#8242;-dCF3bpy)PF6
Brand: SIAL

≥95%, powder

别名:

Photocatalyst

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:

C₃₆H₂₂F₁₆IrN₄P

化学文摘社编号:

2229858-27-7

分子量:

1037.75

MDL number:

MFCD32857514

NACRES:

NA.22

UNSPSC Code:

12161602

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

产品名称

Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆, ≥95%

assay

≥95%

form

powder

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

SMILES string

FC1=CC(F)=C2C3=CC=C(C=[N]3[Ir+3]45([C-]2=C1)([C-]6=CC(F)=CC(F)=C6C7=CC=C(C=[N]74)C)[N]8=CC=C(C=C8C=9C=C(C=C[N]95)C(F)(F)F)C(F)(F)F)C.[F-][P+5]([F-])([F-])([F-])([F-])[F-]

InChI

InChI=1S/C12H6F6N2.2C12H8F2N.F6P.Ir/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18;2*1-8-2-5-12(15-7-8)10-4-3-9(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;3*-1;+3

InChI key

RYKRFKQFYGHADE-UHFFFAOYSA-N

说明

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF₃ and aryl-CF₃ in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF₃ (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKCJ9415

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes.

Chip Le et al.

Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)

Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

全球贸易项目编号

货号	GTIN
902225-500MG	04061838635501
902225-100MG	04061838635495